Synthesis, structure, and properties of a bay-fluorinated triphenylene

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  • Ryu Yoshida
    Institute for Molecular Science , Myodaiji, Okazaki, 444-8787 , Japan
  • Haruki Sugiyama
    Institute for Molecular Science , Myodaiji, Okazaki, 444-8787 , Japan
  • Yasutomo Segawa
    Institute for Molecular Science , Myodaiji, Okazaki, 444-8787 , Japan

書誌事項

公開日
2024-03-12
資源種別
journal article
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1093/chemle/upae048
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>The synthesis, structure, and electronic properties of a bay-fluorinated triphenylene are reported. 2,3,6,7,10,11-Hexaethoxy-1,4,5,8,9,12-hexafluorotriphenylene (1) was synthesized via the 6-fold deprotonation and electrophilic fluorination of hexaethoxytriphenylene (2). X-ray crystallography revealed a distorted structure and columnar stacking for 1. The steric and electronic properties of 1 were examined by using photophysical measurements and theoretical calculations.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 53 (4), 2024-03-12

    Oxford University Press (OUP)

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