Mechanistic origins of accelerated hydrogenation of mixed alkylaromatics by synchronised adsorption over Rh/SiO<sub>2</sub>

DOI Web Site 1 Citations 43 References Open Access
  • Nikolay Cherkasov
    School of Engineering, University of Warwick, Coventry, CV4 7AL, UK
  • Shusaku Asano
    Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga 816-8580, Japan
  • Yuta Tsuji
    Faculty of Engineering Sciences, Kyushu University, Kasuga 816-8580, Japan
  • Kazuki Okazawa
    Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan
  • Kazunari Yoshizawa
    Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan
  • Hiroyuki Miyamura
    Interdisciplinary Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan
  • Jun-ichiro Hayashi
    Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga 816-8580, Japan
  • Alexander A. Kunitsa
    Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA
  • S. David Jackson
    Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow G12 8QQ, UK

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<jats:p>We have studied the unique reaction acceleration phenomenon in the mixture and discussed the limitations of the Langmuir–Hinshelwood model for a solid-catalysed reaction.</jats:p>

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