{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360021393800629632.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.202307140"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202307140"}}],"dc:title":[{"@value":"Isostructural Nanocluster Manipulation Reveals Pivotal Role of One Surface Atom in Click Chemistry"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Elucidating single‐atom effects on the fundamental properties of nanoparticles is challenging because single‐atom modifications are typically accompanied by appreciable changes to the overall particle's structure. Herein, we report the synthesis of a [Cu<jats:sub>58</jats:sub>H<jats:sub>20</jats:sub>PET<jats:sub>36</jats:sub>(PPh<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>]<jats:sup>2+</jats:sup> (<jats:bold>Cu<jats:sub>58</jats:sub></jats:bold>; PET: phenylethanethiolate; PPh<jats:sub>3</jats:sub>: triphenylphosphine) nanocluster—an atomically precise nanoparticle—that can be transformed into the surface‐defective analog [Cu<jats:sub>57</jats:sub>H<jats:sub>20</jats:sub>PET<jats:sub>36</jats:sub>(PPh<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>]<jats:sup>+</jats:sup> (<jats:bold>Cu<jats:sub>57</jats:sub></jats:bold>). Both nanoclusters are virtually identical, with five concentric metal shells, save for one missing surface copper atom in <jats:bold>Cu<jats:sub>57</jats:sub></jats:bold>. Remarkably, the loss of this single surface atom drastically alters the reactivity of the nanocluster. In contrast to <jats:bold>Cu<jats:sub>58</jats:sub></jats:bold>, <jats:bold>Cu<jats:sub>57</jats:sub></jats:bold> shows promising activity for click chemistry, particularly photoinduced [3+2] azide‐alkyne cycloaddition (AAC), which is attributed to the active catalytic site in <jats:bold>Cu<jats:sub>57</jats:sub></jats:bold> after the removal of one surface copper atom. Our study not only presents a unique system for uncovering the effect of a single‐surface atom modification on nanoparticle properties but also showcases single‐atom surface modification as a powerful means for designing nanoparticle catalysts.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380021393800629635","@type":"Researcher","foaf:name":[{"@value":"Arunachalam Sagadevan"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629643","@type":"Researcher","foaf:name":[{"@value":"Atanu Ghosh"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629639","@type":"Researcher","foaf:name":[{"@value":"Omar F. Mohammed"}],"jpcoar:affiliationName":[{"@value":"Advanced Membranes and Porous Materials Center (AMPMC) KAUST Catalysis Center (KCC) Physical Sciences and Engineering Division King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629632","@type":"Researcher","foaf:name":[{"@value":"Chunwei Dong"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629638","@type":"Researcher","foaf:name":[{"@value":"Badriah Alamer"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629640","@type":"Researcher","foaf:name":[{"@value":"Irshad Hussain"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry & Chemical Engineering Syed Babar Ali School of Science & Engineering Lahore University of Management Sciences (LUMS), DHA  54792 Lahore Pakistan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629633","@type":"Researcher","foaf:name":[{"@value":"Ren‐Wu Huang"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629642","@type":"Researcher","foaf:name":[{"@value":"Luis Gutiérrez‐Arzaluz"}],"jpcoar:affiliationName":[{"@value":"Advanced Membranes and Porous Materials Center (AMPMC) KAUST Catalysis Center (KCC) Physical Sciences and Engineering Division King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629637","@type":"Researcher","foaf:name":[{"@value":"Magnus Rueping"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629641","@type":"Researcher","foaf:name":[{"@value":"Peng Yuan"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629636","@type":"Researcher","foaf:name":[{"@value":"Saidkhodzha Nematulloev"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021393800629634","@type":"Researcher","foaf:name":[{"@value":"Osman M. Bakr"}],"jpcoar:affiliationName":[{"@value":"KAUST Catalysis Center (KCC) Division of Physical Sciences and Engineering King Abdullah University of Science and Technology (KAUST)  23955-6900 Thuwal Saudi Arabia"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2023-08-03","prism:volume":"62","prism:number":"37","prism:startingPage":"e202307140"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202307140"}],"createdAt":"2023-07-20","modifiedAt":"2024-01-23","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360025430205507840","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Tunable structural rearrangement in Cu cluster assemblies through linker and solvent alterations"}]},{"@id":"https://cir.nii.ac.jp/crid/1360025430650816128","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cu-Nanoclusters as Emerging Catalyst in Organic Synthesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360584340538619648","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A Comprehensive Analysis of Luminescent Crystallized Cu Nanoclusters"}]},{"@id":"https://cir.nii.ac.jp/crid/1360584340721109632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Advances in Cu nanocluster catalyst design: recent progress and promising applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869855124150400","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Exploring the impact of various reducing agents on Cu nanocluster synthesis"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869856046328448","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Highly Selective Methanol Synthesis Using Electrochemical CO<sub>2</sub> Reduction with Defect‐Engineered Cu<sub>58</sub> Nanoclusters"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869856053382912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Luminescent Hydride-Free [Cu<sub>7</sub>(SC<sub>5</sub>H<sub>9</sub>)<sub>7</sub>(PPh<sub>3</sub>)<sub>3</sub>] Nanocluster: Facilitating Highly Selective C–C Bond Formation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869856054365824","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Exploring the structural evolution of Cu–thiolate nanoclusters and their property correlations"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.202307140"},{"@type":"CROSSREF","@value":"10.1039/d4sc07730j_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1055/a-2504-3530_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1021/acs.jpclett.3c03374_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1039/d3nh00336a_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1039/d4dt00296b_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1002/smsc.202400465_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1021/jacs.4c05678_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"},{"@type":"CROSSREF","@value":"10.1039/d4cc06139j_references_DOI_Zj3D2DHZQpS5A9sH00bZ7rSRftA"}]}