{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360021395962224128.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/aenm.202203790"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.202203790"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/aenm.202203790"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.202203790"}}],"dc:title":[{"@value":"Tuning Ion Transport at the Anode‐Electrolyte Interface via a Sulfonate‐Rich Ion‐Exchange Layer for Durable Zinc‐Iodine Batteries"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Rechargeable aqueous zinc‐iodine batteries (ZIBs) are considered a promising newly‐developing energy‐storage system, but the corrosion and dendritic growth occurring on the anode seriously hinder their future application. Here, the corrosion mechanism of polyiodide is revealed in detail, showing that it can spontaneously react with zinc and cause rapid battery failure. To address this issue, a sulfonate‐rich ion‐exchange layer (SC‐PSS) is purposely constructed to modulate the transport and reaction chemistry of polyiodide and Zn<jats:sup>2+</jats:sup> at the zinc/electrolyte interface. The resulting ZIBs can work properly over 6000 cycles with high‐capacity retention (90.2%) and reversibility (99.89%). Theoretical calculations and experimental characterization reveal that the SC‐PPS layer blocks polyiodide permeation through electrostatic repulsion, while facilitating desolvation of Zn(H<jats:sub>2</jats:sub>O)<jats:sub>6</jats:sub><jats:sup>2+</jats:sup> and restricting undesirable 2D diffusion of Zn<jats:sup>2+</jats:sup> by chemisorption.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380021395962224139","@type":"Researcher","foaf:name":[{"@value":"Leiqian Zhang"}],"jpcoar:affiliationName":[{"@value":"School of Chemical Engineering Zhengzhou University  Zhengzhou 450001 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224137","@type":"Researcher","foaf:name":[{"@value":"Jiajia Huang"}],"jpcoar:affiliationName":[{"@value":"School of Chemical Engineering Zhengzhou University  Zhengzhou 450001 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224136","@type":"Researcher","foaf:name":[{"@value":"Hele Guo"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry KU Leuven  Celestijnenlaan 200F 3001 Leuven Belgium"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224135","@type":"Researcher","foaf:name":[{"@value":"Lingfeng Ge"}],"jpcoar:affiliationName":[{"@value":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224131","@type":"Researcher","foaf:name":[{"@value":"Zhihong Tian"}],"jpcoar:affiliationName":[{"@value":"Engineering Research Center for Nanomaterials Henan University  Kaifeng 475004 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224132","@type":"Researcher","foaf:name":[{"@value":"Mingjie Zhang"}],"jpcoar:affiliationName":[{"@value":"School of Chemical Engineering Zhengzhou University  Zhengzhou 450001 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224134","@type":"Researcher","foaf:name":[{"@value":"Guanjie He"}],"jpcoar:affiliationName":[{"@value":"Electrochemical Innovation Lab Department of Chemical Engineering University College London  London WC1E 7JE UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224138","@type":"Researcher","foaf:name":[{"@value":"Tianxi Liu"}],"jpcoar:affiliationName":[{"@value":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi 214122 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224128","@type":"Researcher","foaf:name":[{"@value":"Johan Hofkens"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry KU Leuven  Celestijnenlaan 200F 3001 Leuven Belgium"},{"@value":"Department of Molecular Spectroscopy Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224129","@type":"Researcher","foaf:name":[{"@value":"Dan J.L. Brett"}],"jpcoar:affiliationName":[{"@value":"Electrochemical Innovation Lab Department of Chemical Engineering University College London  London WC1E 7JE UK"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224133","@type":"Researcher","foaf:name":[{"@value":"Jingtao Wang"}],"jpcoar:affiliationName":[{"@value":"School of Chemical Engineering Zhengzhou University  Zhengzhou 450001 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380021395962224130","@type":"Researcher","foaf:name":[{"@value":"Feili Lai"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry KU Leuven  Celestijnenlaan 200F 3001 Leuven Belgium"},{"@value":"Department of Molecular Spectroscopy Max Planck Institute for Polymer Research  Ackermannweg 10 55128 Mainz Germany"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"16146832"},{"@type":"EISSN","@value":"16146840"}],"prism:publicationName":[{"@value":"Advanced Energy Materials"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2023-02-05","prism:volume":"13","prism:number":"13"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.202203790"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/aenm.202203790"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.202203790"}],"createdAt":"2023-02-05","modifiedAt":"2025-10-07","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360865814747912192","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Lithiation Enhances Electrocatalytic Iodine Conversion and Polyiodide Confinement in Iodine Host for Zinc–Iodine Batteries"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/aenm.202203790"},{"@type":"CROSSREF","@value":"10.1002/adfm.202304811_references_DOI_PshpbA4nkdEWjUQJLspQ2kgFxS6"}]}