{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360022305565638784.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.26434/chemrxiv.12496736.v1"}},{"identifier":{"@type":"URI","@value":"https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/60c74c8abdbb89cf7da397ee/original/amino-functionalization-of-vinyl-substituted-aromatic-diimides-by-quantitative-and-catalyst-free-hydroamination.pdf"}},{"identifier":{"@type":"DOI","@value":"10.1002/chem.202003628"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.202003628"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202003628"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202003628"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202003628"}},{"identifier":{"@type":"DOI","@value":"10.26434/chemrxiv.12496736"}},{"identifier":{"@type":"URI","@value":"https://ndownloader.figshare.com/files/23182487"}},{"identifier":{"@type":"PMID","@value":"32896917"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Amino-Functionalization of Vinyl-Substituted Aromatic Diimides by Quantitative and Catalyst-Free Hydroamination"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n                  <jats:p>Development of facile and versatile synthetic tools for decorating π‐conjugated molecules has attracted considerable interest because of their potential application in creating novel functional π‐systems. Reported herein are quantitative catalyst‐free hydroamination reactions of a series of aromatic diimide compounds having vinyl groups at the π‐core, which have been confirmed by NMR, UV‐vis absorption spectroscopy, mass analysis, and single‐crystal X‐ray structural analysis. Kinetic studies revealed that the hydroamination reaction of a vinyl‐substituted naphthalenediimide with an aliphatic amine proceeded rapidly under benign conditions. Similarly, the two vinyl groups attached to aromatic diimides reacted with amines simultaneously, resulting in the formation of amine bisadducts and macromolecules. An amino group appended perylenediimide through an ethylene spacer at the π‐core exhibited distinct fluorescence switching in response to acid and base.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380022305565638785","@type":"Researcher","foaf:name":[{"@value":"Haruki SANEMATSU"}]},{"@id":"https://cir.nii.ac.jp/crid/1380022305565638787","@type":"Researcher","foaf:name":[{"@value":"Yoshitaka Matsushita"}]},{"@id":"https://cir.nii.ac.jp/crid/1380022305565638784","@type":"Researcher","foaf:name":[{"@value":"Masayuki TAKEUCHI"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276190947584","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90746728"},{"@type":"NRID","@value":"1000090746728"},{"@type":"ORCID","@value":"0000-0003-3457-3352"},{"@type":"NRID","@value":"9000379609799"},{"@type":"NRID","@value":"9000283123305"},{"@type":"NRID","@value":"9000383743578"}],"foaf:name":[{"@value":"Atsuro TAKAI"}],"jpcoar:affiliationName":[{"@value":"National Institute for Materials Science (NIMS)"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"American Chemical Society 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of functional pi-conjugated molecules and their assemblies by novel catalyst-free click reactions"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360009142687242368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Catalyst‐Free π‐Extended Conjugate Addition of Amines to Various Electron‐Deficient π‐Systems"}]},{"@id":"https://cir.nii.ac.jp/crid/1360009142687298432","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Immobilization of Ethynyl‐π‐Extended Electron Acceptors with Amino‐Terminated SAMs by Catalyst‐Free Click Reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144464499072","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Morphology of Large ZSM-5 Crystals Unraveled by Fluorescence 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