{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360283691636690688.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jacs.5b06707"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5b06707"}},{"identifier":{"@type":"PMID","@value":"26323169"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Immobilizing Extremely Catalytically Active Palladium Nanoparticles to Carbon Nanospheres: A Weakly-Capping Growth Approach"}],"description":[{"notation":[{"@value":"Ultrafine palladium nanoparticles (Pd NPs) supported on carbon nanospheres have been successfully synthesized using a facile methanol-mediated weakly-capping growth approach (WCGA) with anhydrous methanol as a mild reductant and a weakly capping agent. The Pd NPs show exceedingly high catalytic activity for 100% selective dehydrogenation of aqueous formic acid (FA) at ambient temperatures. The small size and clean surface of the Pd NPs greatly improve the catalytic properties of the as-prepared catalyst, providing an average rate of CO-free H2 generation up to 43 L H2 gPd(-1) min(-1) and a turnover frequency of 7256 h(-1) at 60 °C. These values are much higher than those obtained even with the most active catalyst reported thus far for heterogeneously catalyzed dehydrogenation of FA. This remarkably facile and effective methanol-mediated WCGA provides a powerful entry into ultrafine metal NPs with clean surface to achieve enhanced performance. Moreover, the catalytic results open up new avenues in the effective applications of FA for hydrogen storage."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380566394800014209","@type":"Researcher","foaf:name":[{"@value":"Qi-Long Zhu"}],"jpcoar:affiliationName":[{"@value":"National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751159585536","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20390437"},{"@type":"NRID","@value":"1000020390437"},{"@type":"NRID","@value":"9000018320084"},{"@type":"NRID","@value":"9000000975682"},{"@type":"NRID","@value":"9000256021147"},{"@type":"NRID","@value":"9000256022011"},{"@type":"NRID","@value":"9000006651656"},{"@type":"NRID","@value":"9000252842623"},{"@type":"NRID","@value":"9000000081159"},{"@type":"NRID","@value":"9000000976004"},{"@type":"NRID","@value":"9000019053231"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/ntsumroi"}],"foaf:name":[{"@value":"Nobuko Tsumori"}],"jpcoar:affiliationName":[{"@value":"National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan"},{"@value":"Toyama National College of Technology, 13, Hongo-machi, Toyama, 939-8630, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380566394800014210","@type":"Researcher","foaf:name":[{"@value":"Qiang Xu"}],"jpcoar:affiliationName":[{"@value":"National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2015-09-08","prism:volume":"137","prism:number":"36","prism:startingPage":"11743","prism:endingPage":"11748"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5b06707"}],"createdAt":"2015-09-01","modifiedAt":"2023-04-14","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782427707520","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"13F03509"},{"@type":"JGN","@value":"JP13F03509"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13F03509/"}],"notation":[{"@language":"ja","@value":"高性能ホウ素－窒素系水素貯蔵材料の研究"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257232627840","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"25420829"},{"@type":"JGN","@value":"JP25420829"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25420829/"}],"notation":[{"@language":"ja","@value":"金属ナノ粒子の触媒機能と応用についての研究"},{"@language":"en","@value":"Study of metal nanoparticle catalysts - function and application -"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216611260416","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Evolution of the PVP–Pd Surface Interaction in Nanoparticles through the Case Study of Formic Acid Decomposition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216615254144","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Diamine-Alkalized Reduced Graphene Oxide: Immobilization of Sub-2 nm Palladium Nanoparticles and Optimization of Catalytic Activity for Dehydrogenation of Formic Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216658909312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Immobilizing Highly Catalytically Active Noble Metal Nanoparticles on Reduced Graphene Oxide: A Non-Noble Metal Sacrificial Approach"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145657001728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"B-Doped Pd Catalyst: Boosting Room-Temperature Hydrogen Production from Formic Acid–Formate Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021390567481600","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Size effects in plasmonic gold nanorod based Pd-rGO hybrid catalyst for promoting visible-light-driven Suzuki-Miyaura coupling reaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691635166464","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal–Organic Framework: A Double Solvents Approach"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691798857856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Recent strategies targeting efficient hydrogen production from chemical hydrogen storage materials over carbon-supported catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708557527552","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Sodium hydroxide-assisted growth of uniform Pd nanoparticles on nanoporous carbon MSC-30 for efficient and complete dehydrogenation of formic acid under ambient conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1360287144139477376","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"New Approaches Toward the Hydrogen Production From Formic Acid Dehydrogenation Over Pd-Based Heterogeneous Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619896004864","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Liquid Organic Hydrogen Carriers as an efficient vector for the transport and storage of renewable energy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620500842368","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621065573376","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis of “Clean” and Well-Dispersive Pd Nanoparticles with Excellent Electrocatalytic Property on Graphene Oxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621197832064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal–organic framework composites"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292621498061824","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"New approaches to hydrogen storage"}]},{"@id":"https://cir.nii.ac.jp/crid/1360294643760056704","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Continuous-flow synthesis of Pd@Pt core-shell nanoparticles"}]},{"@id":"https://cir.nii.ac.jp/crid/1360564064114006912","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Size and Structure Matter: Enhanced CO<sub>2</sub> Photoreduction Efficiency by Size-Resolved Ultrafine Pt Nanoparticles on TiO<sub>2</sub> Single Crystals"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565166589227776","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pd and Pd–Ag Nanoparticles within a Macroreticular Basic Resin: An Efficient Catalyst for Hydrogen Production from Formic Acid Decomposition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183078132224","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Screening of Carbon-Supported PdAg Nanoparticles in the Hydrogen Production from Formic Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183585689984","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A solvent-switched <i>in situ</i> confinement approach for immobilizing highly-active ultrafine palladium nanoparticles: boosting catalytic hydrogen evolution"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093991551232","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"High‐Temperature‐Stable and Regenerable Catalysts: Platinum Nanoparticles in Aligned Mesoporous Silica Wells"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094576637184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalysis with Transition Metal Nanoparticles in Colloidal Solution:  Nanoparticle Shape Dependence and Stability"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095674024064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Applications of Colloidal Inorganic Nanoparticles: From Medicine to Energy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095830711808","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Charge/Discharge Device for Chemical Hydrogen Storage and Generation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360583260246522880","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"High-pressure hydrogen generation from dehydrogenation of formic acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846639393024640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Palladium Copper Chromium Ternary Nanoparticles Constructed In situ within a Basic Resin: Enhanced Activity in the Dehydrogenation of Formic Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641588758912","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Importance of Acid–Base Equilibrium in Electrocatalytic Oxidation of Formic Acid on Platinum"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641806777472","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Liquid-phase chemical hydrogen storage materials"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658079228928","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Tandem Nitrogen Functionalization of Porous Carbon: Toward Immobilizing Highly Active Palladium Nanoclusters for Dehydrogenation of Formic Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570976371968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent advances in the homogeneous hydrogenation of carbon dioxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861707385848704","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Design of Au nanorods-based plasmonic catalyst in combination with nanohybrid Pd-rGO layer for boosting CO2 hydrogenation to formic acid under visible light irradiation"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044216126848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137044732404608","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen generation from formic acid and alcohols using homogeneous catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045230704512","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137045875820288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Formic Acid Oxidation at Pt/H<sub>2</sub>O Interface from Periodic DFT Calculations Integrated with a Continuum Solvation Model"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519977754880","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"B–N compounds for chemical hydrogenstorage"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520098203648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen-storage materials for mobile applications"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520275238016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520433131904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Structure Sensitivity of Carbon−Nitrogen Ring Opening: Impact of Platinum Particle Size from below 1 to 5 nm upon Pyrrole Hydrogenation Product Selectivity over Monodisperse Platinum Nanoparticles Loaded onto Mesoporous Silica"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520670446464","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Dendrimer-Encapsulated Metal Nanoparticles:  Synthesis, Characterization, and Applications to Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521091754752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reduced Transition Metal Colloids:  A Novel Family of Reusable Catalysts?"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521439378304","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"In Situ Controllable Loading of Ultrafine Noble Metal Particles on Titania"}]},{"@id":"https://cir.nii.ac.jp/crid/1361694367878357632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"PdAg Nanoparticles Supported on Functionalized Mesoporous Carbon: Promotional Effect of Surface Amine Groups in Reversible Hydrogen Delivery/Storage Mediated by Formic Acid/CO<sub>2</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994867027200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photochemically Engineering the Metal–Semiconductor Interface for Room‐Temperature Transfer Hydrogenation of Nitroarenes with Formic Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995700936448","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"High capacity hydrogenstorage materials: attributes for automotive applications and techniques for materials discovery"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699996209408000","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Multifunctional Au–Co@CN Nanocatalyst for Highly Efficient Hydrolysis of Ammonia Borane"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469741829632","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470578755456","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Combined Surface-Enhanced Infrared Spectroscopy and First-Principles Study on Electro-Oxidation of Formic Acid at Sb-Modified Pt Electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470928716160","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Boron–nitrogen–hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470949766272","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetic and thermodynamic investigation of hydrogen release from ethane 1,2-di-amineborane"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471127023488","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Breakthroughs in Hydrogen Storage—Formic Acid as a Sustainable Storage Material for Hydrogen"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944388449280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Catalytic Hydrogenation of <i>p</i>-Nitrocumene in a Slurry Reactor"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945103451520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945986668800","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Formic acid as a hydrogen source – recent developments and future trends"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262946412232192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott–Schottky heterojunctions for catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418310931200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An Aqueous Rechargeable Formate‐Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418520485888","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mesoporous g-C3N4 nanorods as multifunctional supports of ultrafine metal nanoparticles: hydrogen generation from water and reduction of nitrophenol with tandem catalysis in one step"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418591339520","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Naked metal nanoparticles from metal carbonyls in ionic liquids: Easy synthesis and stabilization"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419364828928","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419453434752","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419613812736","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Available hydrogen from formic acid decomposed by rare earth elements promoted Pd‐Au/C catalysts at low temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419938714624","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanisms of Nucleation and Growth of Nanoparticles in Solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420506129280","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen production from formic acid decomposition at room temperature using a Ag–Pd core–shell nanocatalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420843985664","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"CO<sub>2</sub>‐“Neutral” Hydrogen Storage Based on Bicarbonates and Formates"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894187782272","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Viable Hydrogen‐Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894930772096","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"“Click” Polymer‐Supported Palladium Nanoparticles as Highly Efficient Catalysts for Olefin Hydrogenation and Suzuki Coupling Reactions under Ambient Conditions"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895090255104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ultrafast Microwave-Assisted Route to Surfactant-Free Ultrafine Pt Nanoparticles on Graphene: Synergistic Co-reduction Mechanism and High Catalytic Activity"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107368400245632","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845068521984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Theoretical Elucidation of the Competitive Electro-oxidation Mechanisms of Formic Acid on Pt(111)"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845574998656","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Core–Shell Catalysts of Metal Nanoparticle Core and Metal–Organic Framework Shell"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388846149818112","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen storage in metal–organic frameworks"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319517207296","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemical hydrogen storage: ‘material’ gravimetric capacity versus‘system’ gravimetric capacity"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319850485504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H<sub>2</sub> and CO<sub>2</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319983424640","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Towards the development of a hydrogen battery"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320401217536","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Highly Efficient Dehydrogenation of Formic Acid over a Palladium‐Nanoparticle‐Based Mott–Schottky Photocatalyst"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320742721152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Well‐Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320973804416","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"An Efficient CoAuPd/C Catalyst for Hydrogen Generation from Formic Acid at Room Temperature"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951794996373888","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen storage: beyond conventional methods"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233268294730112","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Immobilizing Metal Nanoparticles to Metal–Organic Frameworks with Size and Location Control for Optimizing Catalytic Performance"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233268667935104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Facile Preparation of Transition Metal Nanoparticles Stabilized by Well-Defined (Co)polymers Synthesized via Aqueous Reversible Addition-Fragmentation Chain Transfer Polymerization"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233269274590336","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Nano-architecture and material designs for water splitting photoelectrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270062992640","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemical and Physical Solutions for Hydrogen Storage"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270878945920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal-free dehydrogenation of formic acid to H<sub>2</sub>and CO<sub>2</sub>using boron-based catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1524232505173732480","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Account/Review for Materials Innovation : Metal Nanoparticle-Catalyzed Hydrogen Generation from Liquid Chemical Hydrides"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/jacs.5b06707"},{"@type":"KAKEN","@value":"PRODUCT-20480284"},{"@type":"KAKEN","@value":"PRODUCT-20530564"},{"@type":"OPENAIRE","@value":"doi_dedup___::8928ca9130c513f5692f24631ad4d3e8"},{"@type":"CROSSREF","@value":"10.1039/d3su00149k_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1016/j.cattod.2022.05.028_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1038/s41427-018-0025-6_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.3389/fmats.2019.00044_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1016/j.colsurfa.2021.126607_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1039/c8ta01093e_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1021/acscatal.7b04099_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1021/acs.iecr.6b01635_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20180227_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1002/cctc.201700595_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1021/acscatal.7b00053_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1016/j.cattod.2022.06.010_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"},{"@type":"CROSSREF","@value":"10.1021/acs.langmuir.6b03149_references_DOI_GsqL0EqkH8BxgrYQMgpmzEJNiEq"}]}