{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360283691636734336.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jacs.5b10491"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5b10491"}},{"identifier":{"@type":"PMID","@value":"26876504"}},{"identifier":{"@type":"HANDLE","@value":"11245.1/82c38c87-35d9-4946-9d22-a7ab4cb7cf3f"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"An Adsorbate Discriminatory Gate Effect in a Flexible Porous Coordination Polymer for Selective Adsorption of CO<sub>2</sub> over C<sub>2</sub>H<sub>2</sub>"}],"description":[{"notation":[{"@value":"The adsorptive separation of C2H2 and CO2 via porous materials is nontrivial due to the close similarities of their boiling points and kinetic diameters. In this work, we describe a new flexible porous coordination polymer (PCP) [Mn(bdc)(dpe)] (H2bdc = 1,4-benzenedicarboxylic acid, dpe = 1,2-di(4-pyridyl)ethylene) having zero-dimensional pores, which shows an adsorbate discriminatory gate effect. The compound shows gate opening type abrupt adsorption for C2H2 but not for CO2, leading to an appreciable selective adsorption of CO2 over C2H2 at near ambient temperature (273 K). The origin of this unique selectivity, as unveiled by in situ adsorption-X-ray diffraction experiments and density functional theory calculations, is due to vastly different orientations between the phenylene ring of bdc and each gas in the nanopores. The structural change by photochemical transformation of this PCP via [2 + 2] photodimerization leads to the removal of inverse CO2/C2H2 selectivity, verifying the mechanism of the guest discriminatory gate effect."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380284919823352454","@type":"Researcher","foaf:name":[{"@value":"Maw Lin Foo"}],"jpcoar:affiliationName":[{"@value":"Institute\rfor Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352451","@type":"Researcher","foaf:name":[{"@value":"Ryotaro Matsuda"}],"jpcoar:affiliationName":[{"@value":"Institute\rfor Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"},{"@value":"Department\rof Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan"},{"@value":"Japan\rScience and Technology Agency (JST), PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan"},{"@value":"RIKEN SPring-8 center, 1-1-1\rKouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352453","@type":"Researcher","foaf:name":[{"@value":"Yuh Hijikata"}],"jpcoar:affiliationName":[{"@value":"Institute\rof Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa-ku, Nagoya 464-8602, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352457","@type":"Researcher","foaf:name":[{"@value":"Rajamani Krishna"}],"jpcoar:affiliationName":[{"@value":"Van\r’t\rHoff Institute for Molecular Sciences, University of Amsterdam, Science\rPark 904, 1098 XH Amsterdam, The 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Chemistry and Biological Chemistry, Graduate School of\rEngineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352455","@type":"Researcher","foaf:name":[{"@value":"Akihiro Hori"}],"jpcoar:affiliationName":[{"@value":"Institute\rfor Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"},{"@value":"RIKEN SPring-8 center, 1-1-1\rKouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352459","@type":"Researcher","foaf:name":[{"@value":"Jingui Duan"}],"jpcoar:affiliationName":[{"@value":"Institute\rfor Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352456","@type":"Researcher","foaf:name":[{"@value":"Yohei Sato"}],"jpcoar:affiliationName":[{"@value":"RIKEN SPring-8 center, 1-1-1\rKouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan"},{"@value":"Department\rof Physical Science, Graduate School of Science, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352458","@type":"Researcher","foaf:name":[{"@value":"Yoshiki Kubota"}],"jpcoar:affiliationName":[{"@value":"RIKEN SPring-8 center, 1-1-1\rKouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan"},{"@value":"Department\rof Physical Science, Graduate School of Science, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380284919823352450","@type":"Researcher","foaf:name":[{"@value":"Masaki Takata"}],"jpcoar:affiliationName":[{"@value":"RIKEN SPring-8 center, 1-1-1\rKouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan"},{"@value":"Institute\rof Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1\rKatahira, Aoba-ku, Sendai 980-8577, 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Kitagawa"}],"jpcoar:affiliationName":[{"@value":"Institute\rfor Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan"},{"@value":"RIKEN SPring-8 center, 1-1-1\rKouto, Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan"},{"@value":"Department\rof Synthetic Chemistry and Biological Chemistry, Graduate School of\rEngineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2016-02-29","prism:volume":"138","prism:number":"9","prism:startingPage":"3022","prism:endingPage":"3030"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jacs.5b10491"}],"createdAt":"2016-02-15","modifiedAt":"2023-04-22","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782233523456","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"25000007"},{"@type":"JGN","@value":"JP25000007"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-25000007/"}],"notation":[{"@language":"ja","@value":"階層的配位空間の化学"},{"@language":"en","@value":"Chemistry of Hierarchical Coordination Space"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050016107290199936","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Crossover Sorption of C₂H₂/CO₂ and C₂H₆/C₂H₄ in Soft Porous Coordination Networks"},{"@value":"Crossover Sorption of C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> and C<sub>2</sub>H<sub>6</sub>/C<sub>2</sub>H<sub>4</sub> in Soft Porous Coordination Networks"}]},{"@id":"https://cir.nii.ac.jp/crid/1050282813764839424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Carbon dioxide capture and efficient fixation in a dynamic porous coordination polymer"}]},{"@id":"https://cir.nii.ac.jp/crid/1050291768243154944","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Crystal Flexibility Design through Local and Global Motility Cooperation"}]},{"@id":"https://cir.nii.ac.jp/crid/1050293015562064128","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Xylene Recognition in Flexible Porous Coordination Polymer by Guest-Dependent 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