{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360283694075194496.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.39.889"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/39/5/889/55788511/bcsj.39.889.pdf"}},{"identifier":{"@type":"NAID","@value":"130001963420"}}],"dc:title":[{"@value":"The Attempted Cationic Polymerization of 1,1-Dimethylcyclopropane and Phenylcyclopropane"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>1,1-Dimethylcyclopropane and phenylcyclopropane gave the oligomer by aluminum bromide-catalyzed polymerization in n-hexane or in methylene chloride at 0°C. The polymerization reactivity of 1,1-dimethylcyclopropane was lower than that of styrene, and the content of cyclopropane units in their copolymers was decreased by a lowering of the temperature. The polymerization of 1,1-dimethylcyclopropane in the presence of polystyrene gave a graft polymer by chain transfer reaction. The polymerization of the cyclopropanes by a coordinated catalyst, C2H5AlCl2/TiCl3, in n-heptane at room temperature gave polymers with molecular weights of above 1200. The results are discussed in comparison with those of the polymerization of the corresponding vinyl monomers.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1581135652729296514","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020103839"}],"foaf:name":[{"@value":"Shuzo Aoki"}],"jpcoar:affiliationName":[{"@value":"Faculty of Engineering, Osaka City University"}]},{"@id":"https://cir.nii.ac.jp/crid/1581135652729296512","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020103864"}],"foaf:name":[{"@value":"Yoshiyuki Harita"}],"jpcoar:affiliationName":[{"@value":"Faculty of Engineering, Osaka City University"}]},{"@id":"https://cir.nii.ac.jp/crid/1581135652729296640","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020103882"}],"foaf:name":[{"@value":"Takayuki Otsu"}],"jpcoar:affiliationName":[{"@value":"Faculty of Engineering, Osaka City University"}]},{"@id":"https://cir.nii.ac.jp/crid/1581135652729296513","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020103908"}],"foaf:name":[{"@value":"Minoru Imoto"}],"jpcoar:affiliationName":[{"@value":"Faculty of Engineering, Osaka City University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1966-05-01","prism:volume":"39","prism:number":"5","prism:startingPage":"889","prism:endingPage":"892"},"reviewed":"false","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/39/5/889/55788511/bcsj.39.889.pdf"}],"createdAt":"2006-07-19","modifiedAt":"2024-01-18","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360855568969097600","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Synthesis of Some Cyclopropane and Spirane Hydrocarbons<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418518414862848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Ionic grafting"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418521256055680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The thermodynamics of polymerization of cyclic compounds by ring opening"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993482880256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Substituted Styrenes. V. Reaction of Styrene and α-Methylstyrene with Dihalocarbenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544421401032192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Isomerization of Saturated Hydrocarbons. XI.<sup>1</sup> The Isomerization of Alkylcyclopropanes and Alkylcyclobutanes in the Presence of Aluminum Halide Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679112657280","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Syntheses of Isoprenoids from Isoprene. III. The Dimerizations of Dimethylcyclopropanes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.39.889"},{"@type":"CIA","@value":"130001963420"},{"@type":"CROSSREF","@value":"10.1246/bcsj.45.3147_references_DOI_MnPo6Q4ixBzKRxNnQINwmIK7Onm"}]}