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A DUALITY OF MECHANISM IN THE HOMOLYTIC SUBSTITUTION REACTION OF ANTHRONE WITH 1-CYANO-1-METHYLETHYL RADICALS
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- Tsutomu Mitsuhashi
- Department of Chemistry, Faculty of Science, The University of Tokyo
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- Michinori Oki
- Department of Chemistry, Faculty of Science, The University of Tokyo
Bibliographic Information
- Published
- 1978-10
- Rights Information
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/cl.1978.1089
- Publisher
- Oxford University Press (OUP)
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Description
<jats:title>Abstract</jats:title> <jats:p>The mechanism of the homolytic substitution reaction of anthrone with 1-cyano-1-methylethyl radicals has been discussed on the basis of kinetic isotope effects as well as CIDNP. Under non-basic conditions the abstraction-combination mechanism is suggested, whereas the addition-disproportionation mechanism via anthranol prevails under basic conditions.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 7 (10), 1089-1092, 1978-10
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360283694083394176
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- NII Article ID
- 130003516295
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles
- OpenAIRE
