Efficient Dihydroxylation of Naphthalene on Photoirradiated Rutile TiO2 Powder in Solution Containing Hydrogen Peroxide

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  • Jianguang Jia
    Research Center for Photoenergetics of Organic Materials, Osaka University
  • Teruhisa Ohno
    Research Center for Photoenergetics of Organic Materials, Osaka University
  • Michio Matsumura
    Research Center for Photoenergetics of Organic Materials, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>We report on enhanced dihydroxylation of naphthalene on photoirradiated TiO2 particles by addition of H2O2 to the reaction solution. The rate was enhanced by 6–40 times by the addition of H2O2, and the quantum yield reached as high as 76% for rutile TiO2 powders. On the other hand, no such enhancement was observed for anatase TiO2 powders.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 29 (8), 908-909, 2000-08-01

    Oxford University Press (OUP)

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