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Herein, we report the synthesis of three novel diketopyrrolopyrrole (DPP)-based D-A molecules having three different terminal groups (amide, ester, and dicyano) and study their electronic properties. An increase in electron acceptor strength from amide to dicyano leads to a bathochromic shift in absorption. Photoconductivity and field effect transistor (FET) measurements confirmed that a small increase in acceptor strength can result in a large change in the charge transport properties from p-type to n-type. The molecule with an amide group, DPP-amide, exhibited a moderate p-type mobility (1.3 × 10"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380285708123490561","@type":"Researcher","foaf:name":[{"@value":"Samrat Ghosh"}],"jpcoar:affiliationName":[{"@value":"Photosciences and Photonics Section, Chemical Sciences and Technology Division, CSIR−National Institute for Interdisciplinary Science and Technology (CSIR−NIIST), Thiruvananthapuram 695019, India"},{"@value":"Academy of Scientific and Innovative Research (AcSIR), CSIR-NIIST Campus, Thiruvananthapuram 695019, India"}]},{"@id":"https://cir.nii.ac.jp/crid/1380285708123490562","@type":"Researcher","foaf:name":[{"@value":"Reshma Raveendran"}],"jpcoar:affiliationName":[{"@value":"School of Physics, Indian Institute of Science Education and Research-Thiruvananthapuram (IISER-TVM), Thiruvananthapuram 695551, 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