{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360285708881123712.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.4739273"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/1.4739273/14078068/064311_1_online.pdf"}},{"identifier":{"@type":"PMID","@value":"22897277"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Stereo correlated dynamics in the energy transfer process of aligned N2 (A 3Σu+) + oriented NO (X 2Π, Ω = 1/2) → NO (A 2Σ+) + N2 (X 1Σg+)"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Steric effect for the NO (A 2Σ+) formation in the aligned N2 (A 3Σu+) + oriented NO (X 2Π, Ω = 1/2) reaction has been observed as a function of the mutual orientational configurations between the two molecular reactants in the collision frame. Multidimensional molecular steric opacity function has been determined. A significant NO (X 2Π) alignment dependence is recognized in contrast with little dependence on NO (X 2Π) orientation. The NO alignment selectivity turns out to depend on the N2 (A 3Σu+) alignment: The axial configuration of NO (X 2Π) is favorable for the axial and sideways configurations of N2 (A 3Σu+), while the sideways configuration of NO (X 2Π) is favorable for the oblique configuration of N2 (A 3Σu+) at an orientation angle of ${\\rm \\theta }_{{\\rm v}_{\\rm R} }$θvR ∼ 45°. with respect to the relative velocity (vR).</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380285708881123840","@type":"Researcher","foaf:name":[{"@value":"H. Ohoyama"}],"jpcoar:affiliationName":[{"@value":"Osaka University Department of Chemistry, Graduate School of Science, , Toyonaka, Osaka 560-0043, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380285708881123712","@type":"Researcher","foaf:name":[{"@value":"S. Maruyama"}],"jpcoar:affiliationName":[{"@value":"Osaka University Department of Chemistry, Graduate School of Science, , Toyonaka, Osaka 560-0043, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00219606"},{"@type":"EISSN","@value":"10897690"}],"prism:publicationName":[{"@value":"The Journal of Chemical Physics"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"2012-08-09","prism:volume":"137","prism:number":"6","prism:startingPage":"064311"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/jcp/article-pdf/doi/10.1063/1.4739273/14078068/064311_1_online.pdf"}],"createdAt":"2012-08-10","modifiedAt":"2023-06-20","project":[{"@id":"https://cir.nii.ac.jp/crid/1040282257126456832","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23350008"},{"@type":"JGN","@value":"JP23350008"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23350008/"}],"notation":[{"@language":"ja","@value":"生体分子の立体異性体選別と衝突異性化反応の多次元立体効果の解明"},{"@language":"en","@value":"Selection of geometric isomer of biomolecules and study of multi-dimensional steric effect on collisional isomerization 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