{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360292620204817536.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.elecom.2004.12.006"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S1388248104003285?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S1388248104003285?httpAccept=text/plain"}}],"dc:title":[{"@value":"Electrocatalytic oxidation of glucose at gold nanoparticle-modified carbon electrodes in alkaline and neutral solutions"}],"description":[{"notation":[{"@value":"Abstract   Electrocatalytic oxidation of glucose in alkaline and neutral solutions was examined using carbon electrodes modified with 2 nm core sized gold nanoparticles (Au 2 nm  nanoparticle). The voltammetric responses for the electrocatalytic oxidation of glucose at Au 2 nm  nanoparticle-modified electrodes in both alkaline and neutral solutions were similar to those at a gold plate electrode. However, the different results were obtained for the electrolysis of glucose between Au 2 nm  nanoparticle-modified and gold plate electrodes. The current flow due to the oxidation of glucose during electrolysis at the gold plate electrode decreased quickly with time, due to the electrode surface poisoning. On the other hand, the decrease in current flow at the Au 2 nm  nanoparticle-modified electrode was much improved in both alkaline and neutral solutions.  The electrolytic oxidation of glucose was performed at Au 2 nm  nanoparticle modified electrodes in both alkaline and neutral solutions. In the alkaline solution, at a potential of −0.3 V, gluconolactone (or gluconate) was formed with a current efficiency of 100%, while at potentials of −0.1 to 0.3 V, oxalate and gluconolactone (or gluconate) were obtained as main products. In a neutral solution, electrolysis at 0.1 and 0.3 V, gluconolactone (or gluconate) was obtained with current efficiencies of 88–100%."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380292620204817536","@type":"Researcher","foaf:name":[{"@value":"Masato Tominaga"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620204817538","@type":"Researcher","foaf:name":[{"@value":"Toshihiro Shimazoe"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620204817539","@type":"Researcher","foaf:name":[{"@value":"Makoto Nagashima"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620204817537","@type":"Researcher","foaf:name":[{"@value":"Isao Taniguchi"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13882481"}],"prism:publicationName":[{"@value":"Electrochemistry Communications"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2005-02","prism:volume":"7","prism:number":"2","prism:startingPage":"189","prism:endingPage":"193"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S1388248104003285?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S1388248104003285?httpAccept=text/plain"}],"createdAt":"2005-01-25","modifiedAt":"2019-01-30","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360017282235004160","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Gold/MnO2 particles decorated on electrodeposited polyaniline toward non-enzymatic electrochemical sensor for glucose"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707046838656","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Size-controlled fabrication of gold nanodome arrays and its application to enzyme electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360286992289675136","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Roles of TiO2 in the highly robust Au nanoparticles-TiO2 modified polyaniline electrode towards non-enzymatic sensing of glucose"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846643577528448","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electrochemical Catalytic Activity of Organic-Inorganic Hybrid Nanoraspberry Consisted of Gold Nanoparticle and Aniline Oligomer"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848655035305600","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Chromatographic Determination of Sugar Probes Used for Gastrointestinal Permeability Test by Employing Nickel‐Copper Nanoalloy Embedded in Carbon Film Electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320636471424","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Modification of boron-doped diamond electrodes with gold–palladium nanoparticles for an oxygen sensor"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204585084160","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Highly Catalytic Electrode for Glucose Electro-oxidation Based on Au Nanoparticles Electrodeposited onto HOPG Substrate"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204585607040","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effective Electrocatalytic Oxidation of Glucose at Platinum Nanoparticle-based Carbon Electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206495761152","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"電極触媒を利用した効率的バイオ燃料電池の構築"},{"@language":"ja-Kana","@value":"デンキョク ショクバイ オ リヨウシタ コウリツテキ バイオ ネンリョウ デンチ ノ コウチク"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679232073216","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Recent Nanoarchitectures in Metal Nanoparticle-modified Electrodes for Electroanalysis"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680274245120","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrochemistry of Biologically Related Metal Complexes and Its Applications"},{"@language":"ja","@value":"生体関連金属錯体の電気化学とその応用"},{"@value":"Award Accounts 生体関連金属錯体の電気化学とその応用"},{"@language":"ja-Kana","@value":"Award Accounts セイタイ カンレン キンゾク サクタイ ノ デンキ カガク ト ソノ オウヨウ"}]},{"@id":"https://cir.nii.ac.jp/crid/2050870367083467136","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"High power sugar fuel cells using PEDOT*PSS, CNT and PtRu composite anode"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714792019829504","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Discharge capacity and energy density in gluconic acid and saccharides fuel cells"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1016/j.elecom.2004.12.006"},{"@type":"OPENAIRE","@value":"doi_dedup___::e6b5697f9d94793bbcb718f6bcadac61"},{"@type":"CROSSREF","@value":"10.1016/j.mne.2023.100175_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.5796/electrochemistry.76.910_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1246/cl.2007.898_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1246/cl.2008.936_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1246/cl.210656_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1149/2.058311jes_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1002/elan.201800072_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.2116/analsci.26.1_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1039/d0an02414g_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1246/cl.220173_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1016/j.talanta.2020.120780_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.1016/j.colsurfa.2011.04.024_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"},{"@type":"CROSSREF","@value":"10.4019/bjscc.55.19_references_DOI_RqGhMrjoHWvGrIVj7krAYRA8dwc"}]}