{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360292620601683072.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1107/s0108768111014534"}},{"identifier":{"@type":"URI","@value":"http://journals.iucr.org/b/issues/2011/03/00/kd5050/kd5050.pdf"}}],"dc:title":[{"@value":"Structure analysis of titanate nanorods by automated electron diffraction tomography"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>A hitherto unknown phase of sodium titanate, NaTi<jats:sub>3</jats:sub>O<jats:sub>6</jats:sub>(OH)·2H<jats:sub>2</jats:sub>O, was identified as the intermediate species in the synthesis of TiO<jats:sub>2</jats:sub> nanorods. This new phase, prepared as nanorods, was investigated by electron diffraction, X-ray powder diffraction, thermogravimetric analysis and high-resolution transmission electron microscopy. The structure was determined <jats:italic>ab initio</jats:italic> using electron diffraction data collected by the recently developed automated diffraction tomography technique. NaTi<jats:sub>3</jats:sub>O<jats:sub>6</jats:sub>(OH)·2H<jats:sub>2</jats:sub>O crystallizes in the monoclinic space group <jats:italic>C</jats:italic>2/<jats:italic>m</jats:italic>. Corrugated layers of corner- and edge-sharing distorted TiO<jats:sub>6</jats:sub> octahedra are intercalated with Na<jats:sup>+</jats:sup> and water of crystallization. The nanorods are typically affected by pervasive defects, such as mutual layer shifts, that produce diffraction streaks along c*. In addition, edge dislocations were observed in HRTEM images.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380292620601683078","@type":"Researcher","foaf:name":[{"@value":"Iryna Andrusenko"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620601683077","@type":"Researcher","foaf:name":[{"@value":"Enrico Mugnaioli"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620601683076","@type":"Researcher","foaf:name":[{"@value":"Tatiana E. Gorelik"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620601683072","@type":"Researcher","foaf:name":[{"@value":"Dominik Koll"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620601683075","@type":"Researcher","foaf:name":[{"@value":"Martin Panthöfer"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620601683074","@type":"Researcher","foaf:name":[{"@value":"Wolfgang Tremel"}]},{"@id":"https://cir.nii.ac.jp/crid/1380292620601683073","@type":"Researcher","foaf:name":[{"@value":"Ute Kolb"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"01087681"}],"prism:publicationName":[{"@value":"Acta Crystallographica Section B Structural Science"}],"dc:publisher":[{"@value":"International Union of Crystallography (IUCr)"}],"prism:publicationDate":"2011-05-14","prism:volume":"67","prism:number":"3","prism:startingPage":"218","prism:endingPage":"225"},"reviewed":"false","dc:rights":["http://journals.iucr.org/services/copyrightpolicy.html","http://journals.iucr.org/services/copyrightpolicy.html#TDM"],"url":[{"@id":"http://journals.iucr.org/b/issues/2011/03/00/kd5050/kd5050.pdf"}],"createdAt":"2011-05-13","modifiedAt":"2025-01-11","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233249458304","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Argentivorous Molecules: Structural Evidence for Ag<sup>+</sup>–π Interactions in Solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658121777792","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Argentivorous Molecules Bearing Two Aromatic Side-Arms: Ag<sup>+</sup>–π and CH−π Interactions in the Solid State and in Solution"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1107/s0108768111014534"},{"@type":"CROSSREF","@value":"10.1021/ol3019538_references_DOI_9CjulXh18uJfhMVN1bw0G6uh2Vi"},{"@type":"CROSSREF","@value":"10.1021/ic302511e_references_DOI_9CjulXh18uJfhMVN1bw0G6uh2Vi"}]}