{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360294646629959936.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.201604675"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201604675"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201604675"}}],"dc:title":[{"@value":"Inverse Kinetic and Equilibrium Isotope Effects on Self‐Assembly and Supramolecular Chirality of Porphyrin J‐Aggregates"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>When mixtures of D<jats:sub>2</jats:sub>O/DCl are used to foster the self‐assembly formation of TPPS<jats:sub>4</jats:sub> porphyrin J‐aggregates in aqueous solutions, an inverse kinetic isotope effect of 0.4 and an inverse equilibrium isotope effect of 0.6 are clearly detected. Most importantly, the addition of at least 10 % D<jats:sub>2</jats:sub>O causes an inversion in the handedness of the final chiral J‐aggregates, thus evidencing an important role of deuterium in driving the enantiomeric excess in the scalemic mixture of such supramolecular assemblies.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380294646629959938","@type":"Researcher","foaf:name":[{"@value":"Roberto Zagami"}],"jpcoar:affiliationName":[{"@value":"CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina  V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294646629959937","@type":"Researcher","foaf:name":[{"@value":"Andrea Romeo"}],"jpcoar:affiliationName":[{"@value":"CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina  V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax"},{"@value":"Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina, and C.I.R.C.M.S.B.  V.le F. Stagno D'Alcontres 31 98166 Messina Italy"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294646629960064","@type":"Researcher","foaf:name":[{"@value":"Maria A. Castriciano"}],"jpcoar:affiliationName":[{"@value":"CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina  V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294646629959936","@type":"Researcher","foaf:name":[{"@value":"Luigi Monsù Scolaro"}],"jpcoar:affiliationName":[{"@value":"CNR-ISMN Istituto per lo Studio dei Materiali Nanostrutturati c/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina  V.le F. Stagno D'Alcontres 31 98166 Messina Italy), Fax"},{"@value":"Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali University of Messina, and C.I.R.C.M.S.B.  V.le F. Stagno D'Alcontres 31 98166 Messina Italy"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2016-11-29","prism:volume":"23","prism:number":"1","prism:startingPage":"70","prism:endingPage":"74"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201604675"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201604675"}],"createdAt":"2016-11-10","modifiedAt":"2025-10-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360013168839067776","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Supramolecular Assembly of Conjugated Polymers under Vibrational Strong Coupling"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/chem.201604675"},{"@type":"CROSSREF","@value":"10.1002/ange.202105840_references_DOI_9257bKOnIJDrwgdlDKJ8AWIYSyv"}]}