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This simple transformation furnishes (<jats:italic>E</jats:italic>)‐2‐alkylvinylphenylsulfones in up to 88 % yield. In contrast with the previously reported decatungstate protocol, the current method is applicable to alkenylation of sterically hindered C−H bonds. This important advantage significantly broadens the substrate scope, and is attributed to the compact size of the sulfate radical employed in the C−H activation and cleavage.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751153123456","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60566298"},{"@type":"NRID","@value":"1000060566298"},{"@type":"NRID","@value":"9000365542574"},{"@type":"NRID","@value":"9000391967711"}],"foaf:name":[{"@value":"Mitsuhiro Ueda"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Graduate School of Science Osaka Prefecture University  Sakai Osaka 599-8531 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294647131462020","@type":"Researcher","foaf:name":[{"@value":"Kazuya Kamikawa"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Graduate School of Science Osaka Prefecture University  Sakai Osaka 599-8531 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