{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360294647774809088.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/macp.201700009"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.201700009"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.201700009"}}],"dc:title":[{"@value":"Strengthening Phosphoric Acid Doped Polybenzimidazole Membranes with Siloxane Networks for Using as High Temperature Proton Exchange Membranes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>Two silane compounds, i.e., ((chloromethyl)phenylethyl)trimethoxysilane (Ph‐Si) and 3‐chloropropyltriethoxysilane (Pr‐Si), are employed as covalent crosslinkers to fabricate high temperature proton exchange membranes based on polybenzimidazole (PBI) in order to better understand the correlation between the structure and the property of the crosslinked membranes. All the crosslinked PBI membranes display longer morphology durability over the neat PBI membrane toward the radical oxidation. The crosslinked membranes with the crosslinker containing a rigid group of phenylene (PBI‐Ph) show superior acid doping level, high conductivity, and excellent mechanical strength simultaneously, comparing to those with the crosslinker having a flexible alkyl chain (PBI‐Pr) and the pristine PBI based membrane. The technical feasibility for using as high temperature proton exchange membranes is demonstrated by the acid doped crosslinked PBI‐Ph membranes via fuel cell tests.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http://www.w3.org/1999/xlink\" mimetype=\"image/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic/macp201700009-abs-0001-m.png\"><jats:alt-text>image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380294647774809089","@type":"Researcher","foaf:name":[{"@value":"Jingshuai Yang"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294647774809091","@type":"Researcher","foaf:name":[{"@value":"Liping Gao"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294647774809088","@type":"Researcher","foaf:name":[{"@value":"Jin Wang"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294647774809093","@type":"Researcher","foaf:name":[{"@value":"Yixin Xu"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294647774809090","@type":"Researcher","foaf:name":[{"@value":"Chao Liu"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380294647774809092","@type":"Researcher","foaf:name":[{"@value":"Ronghuan He"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"10221352"},{"@type":"EISSN","@value":"15213935"}],"prism:publicationName":[{"@value":"Macromolecular Chemistry and Physics"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2017-04-07","prism:volume":"218","prism:number":"10","prism:startingPage":"1700009"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.201700009"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.201700009"}],"createdAt":"2017-04-07","modifiedAt":"2023-10-03","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360013168846435072","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Bipyridine-based polybenzimidazole as a nitrogen-rich ionomer and a platinum nanoparticle support for enhanced fuel cell performance"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/macp.201700009"},{"@type":"CROSSREF","@value":"10.1016/j.fuel.2021.122954_references_DOI_RbemFNX1NPYuNxckYCdHYt5ePap"}]}