Formation and structural analysis of 15MgO–15CaO–8P2O5–4SiO2 glass

DOI Web Site Web Site 5 Citations 34 References

Bibliographic Information

Published
2017-02
Resource Type
journal article
Rights Information
  • https://www.elsevier.com/tdm/userlicense/1.0/
  • https://www.elsevier.com/legal/tdmrep-license
DOI
  • 10.1016/j.jnoncrysol.2016.11.020
Publisher
Elsevier BV

Search this article

Description

Abstract MgO-CaO-P2O5-SiO2 invert glass in the orthophosphate region was successfully prepared using a melt-quenching method, and its structure and dissolution behavior were evaluated. The 31P and 29Si solid-state nuclear magnetic resonance and Raman spectroscopies showed that the glass structure consisted of orthophosphate (Qp0) and orthosilicate (QSi0) tetrahedra cross-linked by cations such as Mg2 + and Ca2 + ions; there were no chain phosphate groups and silicate network structures. MgO present in the glass acts as an intermediate oxide that cross-links Qp0 and QSi0, thereby imparting excellent glass-forming ability. Mg2 + and Ca2 + ions present in the glass were preferentially bonded with silicate and phosphate groups to form S O Mg and P O Ca bonds, respectively. The ions-releasing amount from the glass was higher than that from previously reported phosphate invert glasses.

Journal

Citations (5)*help

See more

References(34)*help

See more

Related Projects

See more

Report a problem

Back to top