{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360565169051908480.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.39.951"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/39/5/951/55788456/bcsj.39.951.pdf"}},{"identifier":{"@type":"NAID","@value":"130001963434"}}],"dc:title":[{"@value":"The Radiolysis of Aqueous Solutions of Potassium Iodide"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>The radiolysis of potassium iodide aqueous solutions has been studied in order to elucidate the contribution of the hydrated electrons to the radiolysis mechanisms. The deaerated and aerated solutions were irradiated by 60Co γ-rays under various conditions, and the yields of iodine, hydrogen peroxide, hydrogen and oxygen were determined. The pH dependences of the initial yields of iodine and hydrogen peroxide in the deaerated solutions are different from the results obtained in the aerated solutions. These results can be reasonably explained by assuming the hydrogen atoms and hydrated electrons to be the reducing species. From an examination of the results, the radiolysis mechanisms of the potassium iodide aqueous solutions have been discussed. The rate constant of the reaction of hydrated electrons for iodine has been calculated to be 5.9×1010 M−1 sec−1.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1581135652729288832","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020226953"}],"foaf:name":[{"@value":"Takeshi Sawai"}],"jpcoar:affiliationName":[{"@value":"Tokyo Metropolitan Isotope Research Center"}]},{"@id":"https://cir.nii.ac.jp/crid/1581135652729288834","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020226965"}],"foaf:name":[{"@value":"Yoshiharu Shinozaki"}],"jpcoar:affiliationName":[{"@value":"Tokyo Metropolitan Isotope Research Center"}]},{"@id":"https://cir.nii.ac.jp/crid/1581135652729288833","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020226975"}],"foaf:name":[{"@value":"Gisuke Meshitsuka"}],"jpcoar:affiliationName":[{"@value":"Tokyo Metropolitan Isotope Research Center"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1966-05-01","prism:volume":"39","prism:number":"5","prism:startingPage":"951","prism:endingPage":"955"},"reviewed":"false","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/39/5/951/55788456/bcsj.39.951.pdf"}],"createdAt":"2006-07-19","modifiedAt":"2024-01-18","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050583082064079488","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Elucidation of poly(vinyl alcohol) and iodide gel dosimeter characteristics by predicting changes in radical concentrations and measuring responsiveness to heavy ion beams"}]},{"@id":"https://cir.nii.ac.jp/crid/1360286992225420544","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Novel radiochromic gel dosimeter based on a polyvinyl alcohol – Iodide complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292619879363328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<b>Absorption Spectrum of the Hydrated Electron in Water and in Aqueous Solutions</b>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574096388676096","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A DETERMINATION OF SOME RATE CONSTANTS FOR THE RADICAL PROCESSES IN THE RADIATION CHEMISTRY OF WATER<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569971155328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Sialic Acid as a Structural Component of Some Mammalian Tissue Cell Surfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137046074873856","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reactions of the hydrated electron"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699994640355456","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Rates of Reaction of the Hydrated Electron in Aqueous Inorganic Solutions<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469470073984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"THE RATE CONSTANTS FOR H ATOM REACTIONS IN AQUEOUS SOLUTIONS<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944774131968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Radiolysis of Deaerated Aqueous Solutions of 2-Propanol Containing Nitrous Oxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945319861504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"EVIDENCE FOR TWO KINDS OF “H ATOMS” IN THE RADIATION CHEMISTRY OF WATER<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419168592256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Pulse Radiolysis Studies. V. Transient Spectra and Rate Constants in Oxygenated Aqueous Solutions<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419654392192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Decomposition of Aqueous Sulfuric Acid Solutions by Cobalt Gamma Rays: II. Yields of Solvent Decomposition and Reducing Radicals from Fe(II) Solutions in 0.4 to 18 M Acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420268059392","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"THE NATURE OF THE REDUCING RADICAL IN WATER RADIOLYSIS<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420418275456","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Yield and Reactivity of Electrons and H Atoms in Irradiated Aqueous Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388844736424960","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Hydrogen Yields in the Radiolysis of Aqueous Solutions<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845101057024","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Production of Iodine from Solutions of Potassium Iodide Irradiated with Hard X-Rays"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845292365312","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Radiolysis of Aqueous Methanol—Sodium Nitrate Solutions<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670318661638016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"On the Radiolysis of Alkali Halides in Aqueous Solutions Saturated with Nitrous Oxide"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319014740864","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Absorption Spectra in Irradiated Water and Some Solutions: Optical Absorptions in Irradiated Water"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320413696512","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Solute scavenging effects in regions of high radical concentration produced in radiation chemistry"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670321245670016","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"<b>Reaction Constants of the Hydrated Electron</b>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795475419776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Decomposition of Water and Aqueous Solutions under Mixed Fast Neutron and γ-Radiation"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233268903277440","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Kinetics of the Dihalide Ions from the Flash Photolysis of Aqueous Alkali Halide Solutions"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233270478047232","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Spectroscopic studies of reactions of the OH radical in aqueous solutions. Reaction of OH with the ferrocyanide ion"}]},{"@id":"https://cir.nii.ac.jp/crid/1364233271017901824","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effects of pH and the Nature of the Primary Species in the Radiolysis of Aqueous Solutions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.39.951"},{"@type":"CIA","@value":"130001963434"},{"@type":"CROSSREF","@value":"10.1016/j.radmeas.2019.106226_references_DOI_VoXjBscJPXfBnKmIVmZ5Am2WkXa"},{"@type":"CROSSREF","@value":"10.1016/j.radphyschem.2022.110167_references_DOI_VoXjBscJPXfBnKmIVmZ5Am2WkXa"}]}