{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360565169055100928.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/bcsj.54.685"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/bcsj/article-pdf/54/3/685/56104450/bcsj.54.685.pdf"}},{"identifier":{"@type":"NAID","@value":"130001987191"}}],"dc:title":[{"@value":"Photodissociation Reaction from Higher Excited Triplet States of [2.2]Paracyclophane"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>The mechanism of photodissociation of [2.2]paracyclophane in glassy solvent at 77 K was studied. It is concluded that the dissociation of the CH2–CH2 bridge occurs from higher triplet states (Tn) via the lowest triplet state as an intermediate. The efficiency of the reaction depends on the characters of Tn states; high from the locally excited state, and low from the charge-transfer state.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1580291227806440962","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020977828"}],"foaf:name":[{"@value":"Shun-ichi Ishikawa"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]},{"@id":"https://cir.nii.ac.jp/crid/1580291227806440961","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020977835"}],"foaf:name":[{"@value":"Junko Nakamura"}],"jpcoar:affiliationName":[{"@value":"The Institute of Physical and Chemical Research"}]},{"@id":"https://cir.nii.ac.jp/crid/1580291227806440960","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000020977838"}],"foaf:name":[{"@value":"Saburo Nagakura"}],"jpcoar:affiliationName":[{"@value":"The Institute for Solid State Physics, The University of Tokyo"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1981-03-01","prism:volume":"54","prism:number":"3","prism:startingPage":"685","prism:endingPage":"686"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/54/3/685/56104450/bcsj.54.685.pdf"}],"createdAt":"2006-07-26","modifiedAt":"2024-01-17","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Chemistry","dc:title":"General Chemistry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219101093504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Transannular Interaction in the Excited Triplet States of [2.2]Paracyclophane and Related Compounds"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144926662144","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":".pi.,.pi.-Biradicaloid hydrocarbons. 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Involvement of upper and/or hot excited singlet and triplet states in a photochemical conversion of a polycyclic cyclobutene to a butadiene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618728508800","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Detailed studies of a one-electron, two-photon ionization in a rigid organic solution at 77.degree.K"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620849811200","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanism of photodissociation of hydroquinone derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644031505152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Observation of Intramolecular Excimer Emission of Benzyl Radical Pair Produced by Photolysis of [2.2]Paracyclophane"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699993779712256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Biphotonic reactions: General characteristics"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419022629888","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photochemistry of higher excited triplet states of benzaldehyde, acetophenone, and benzophenone at 77.deg.K"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894606788992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Macro Rings. XXXII. Photochemistry of [2.2]Paracyclophane<sup>1</sup>"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845504496768","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electronic spectra and electronic structures of [2.2]paracyclophane and related compounds"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/bcsj.54.685"},{"@type":"CIA","@value":"130001987191"},{"@type":"OPENAIRE","@value":"doi_dedup___::1e9a91fee94a99072324a174a2989302"}]}