FLUORIDE-INDUCED 1,2-ELIMINATION OF <i>O</i>-TRIMETHYLSILYLPHENYL TRIFLATE TO BENZYNE UNDER MILD CONDITIONS

DOI DOI PDF 被引用文献78件 参考文献3件
  • Yoshio Himeshima
    Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University 39
  • Takaaki Sonoda
    Research Institute of Industrial Science Kyushu University 86
  • Hiroshi Kobayashi
    Research Institute of Industrial Science Kyushu University 86

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<jats:title>Abstract</jats:title> <jats:p>Fluoride-induced 1,2-elimination of o-trimethylsilylphenyl triflate provided a convenient route to benzyne under mild conditions where detriflation from an intermediary aryl anion appeared to occur in preference to protonation even in the presence of alcohols.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 12 (8), 1211-1214, 1983-08

    Oxford University Press (OUP)

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