{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360565169062415744.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/cl.1994.941"}},{"identifier":{"@type":"URI","@value":"https://academic.oup.com/chemlett/article-pdf/23/5/941/56065917/cl.1994.941.pdf"}},{"identifier":{"@type":"NAID","@value":"130004419423"}}],"dc:title":[{"@value":"The First Synthesis of Bisgermylene and Bisstannylene with Acyclic Structure"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title>\n               <jats:p>A bisgermylene and a bisstannylene with acyclic structure were synthesized for the first time by one-pot, two-step ligand substitution reactions from the corresponding germanium and tin dichlorides. The products were easily isolated by crystallization from diethyl ether and are stable at ambient temperatures under argon. Oxidative addition of the bisgermylene or bisstannylene to organic halides was examined.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1581980078330652929","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000257705696"}],"foaf:name":[{"@value":"Shiro Kobayashi"}],"jpcoar:affiliationName":[{"@value":"Department of Molecular Chemistry and Engineering, Faculty of Engineering, Tohoku University"}]},{"@id":"https://cir.nii.ac.jp/crid/1581980078330652928","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000257705697"}],"foaf:name":[{"@value":"Shaokui Cao"}],"jpcoar:affiliationName":[{"@value":"Department of Molecular Chemistry and Engineering, Faculty of Engineering, Tohoku University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03667022"},{"@type":"EISSN","@value":"13480715"}],"prism:publicationName":[{"@value":"Chemistry Letters"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1994-05-01","prism:volume":"23","prism:number":"5","prism:startingPage":"941","prism:endingPage":"944"},"reviewed":"false","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/chemlett/article-pdf/23/5/941/56065917/cl.1994.941.pdf"}],"createdAt":"2006-04-19","modifiedAt":"2024-01-18","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1361418519292159872","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Poly(germanium enolate): a new class of polymer having a germanium enolate structure in the main chain"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418519295717760","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Chemistry of heavy carbene analogs R2M (M = Si, Ge, Sn). 12. Concerted and nonconcerted insertion reactions of dimethylgermylene into the carbon-halogen bond"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981471188284288","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Germylenes and stannylenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262945624035328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"New germanium-containing polymers via alternating copolymerization of a germylene with p-benzoquinone derivatives"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418609112704","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"“Dibutylmagnesium”, a convenient reagent for the synthesis of useful organic magnesium reagents MgA2 including cyclopentadienyls, aryloxides, and amides. Preparation of Zr(C5H5)Cl3. X-ray structure of [{μ-N(SiMe)3C6H4N}(SiMe3)-o(OEt2)]2"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894053639424","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Insertion reactions of dimethylgermylene, Me2Ge, and their mechanisms as studied by CIDNP"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843562313984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Subvalent group 14 metal compounds XI. Oxidative addition reactions of organic halides or acid anhydrides (including CH4 − Cl , PhBr, BrN(SiMe3)2, ButCOCl, or (CF3CO)2O) to some bivalent group 14 metal amides or alkyls"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670320074892800","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis and structural characterization of the cyclic species [GeN(2,6-iso-Pr2C6H3)]3: the first \"germanazene\""}]},{"@id":"https://cir.nii.ac.jp/crid/1363951796158700160","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Organogermanium species with the metal in low coordination states. Recent results from the Toulouse group"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1246/cl.1994.941"},{"@type":"CIA","@value":"130004419423"},{"@type":"OPENAIRE","@value":"doi_dedup___::d548136894fb56e10d5334f01684a530"}]}