Confocal Laser Scanning Microscope Analysis of Antimony Porphyrin Chromophore Immobilized on Silica-gel Beads

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  • Jin Matsumoto
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Tomokazu Fuchikawa
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Yasuhiro Komiya
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Tomoko Matsumoto
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Yoshiyuki Fueda
    Fuji Silysia Chemical Ltd
  • Tsutomu Shiragami
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Masahide Yasuda
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki

Bibliographic Information

Published
2005-09-28
Rights Information
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/cl.2005.1484
Publisher
Oxford University Press (OUP)

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Description

<jats:title>Abstract</jats:title> <jats:p>Dihydroxoantimony(V) tetraphenylporphyrin chromophore (SbTPP) was immobilized on 3-aminopropyl-silica gel (NH2–SiO2) by the reaction of dihydroxoantimony [4-(N-succinimidyloxycarbonyl)phenyl]triphenylporphyrin with NH2–SiO2. Spectroscopic analysis of the complex by confocal laser scanning microscope suggested the interaction of SbTPP with the residual amino group on SiO2. The photoreaction of the complex with Et2NH induced the demetallation.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 34 (11), 1484-1485, 2005-09-28

    Oxford University Press (OUP)

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