Stimuli‐Responsive Folding and Unfolding of a Polymer Bearing Multiple Cerium(IV) Bis(porphyrinate) Joints: Mechano‐imitation of the Action of a Folding Ruler

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A pivotal guest role: a new porphyrin polymer, poly(PorZn⋅DD) (pink/purple), composed of a porphyrinatozinc and a porphyrin double-decker complex as a repeating unit was synthesized. In poly(PorZn⋅DD), porphyrinatozinc complexes recognize a divalent amine (tan/red) to induce an intramolecular pivoting motion through the rotation of porphyrin double-decker complexes and the polymer undergoes shortening and compaction.

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