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Upon complexation of 2 with ZnCl(2), the disilyne-NHC-ZnCl(2) complex 3 was produced, in which the Si═Si bond adopted the cis geometry."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380567183166184066","@type":"Researcher","foaf:name":[{"@value":"Torahiko Yamaguchi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan, and Institute of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, Sekr. 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C2, D-10623 Berlin, Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1380567183166184064","@type":"Researcher","foaf:name":[{"@value":"Matthias Driess"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan, and Institute of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17 Juni 135, Sekr. 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