{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360567184422847488.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1088/2058-6272/aa5fc6"}},{"identifier":{"@type":"URI","@value":"http://stacks.iop.org/1009-0630/19/i=5/a=055503/pdf"}},{"identifier":{"@type":"URI","@value":"http://stacks.iop.org/1009-0630/19/i=5/a=055503?key=crossref.df6efe641aa813fd825e7f3eb22ac1a6"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"One-step phenol production from a water–toluene mixture using radio frequency in-liquid plasma"}],"description":[{"notation":[{"@value":"The objectives of this research were to understand the process of converting toluene into phenol in a one-step process directly from a water–toluene mixture using the plasma in-liquid method. Experiments were conducted using 27.12 MHz radio frequency (RF) in-liquid plasma to decompose a solution of 30% toluene. Based on the experimental results as evaluated using gas chromatography–mass spectrometry (GC–MS), along with additional analysis by the Gaussian calculation, density functional theory (DFT) hybrid exchange–correlational functional (B3LYP) and 6-311G basis, the phenol generated from toluene was quantified including any by-products. In the experiment, it was found that OH radicals from water molecules produced using RF in-liquid plasma play a significant role in the chemical reaction with toluene. The experimental results suggest that phenol can be directly produced from a water–toluene mixture. The maximum phenol yields were 0.0013% and 0.0038% for irradiation times of 30 s and 60 s, respectively, at 120 W."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380567184422847488","@type":"Researcher","foaf:name":[{"@value":"Muhammad 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