Cold crystallization of water in hydrated poly(2-methoxyethyl acrylate) (PMEA)

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Published
2000
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  • http://doi.wiley.com/10.1002/tdm_license_1.1
DOI
  • 10.1002/1097-0126(200012)49:12<1709::aid-pi601>3.0.co;2-l
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Wiley

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The structure of water associated with poly(2-methoxyethyl acrylate) (PMEA), which is known to exhibit excellent blood compatibility, has been investigated using differential scanning calorimetry (DSC). The total equilibrium water content (EWC) of PMEA was 9.0 wt%. Water in the PMEA could be classified into three types: non-freezing, freezing-bound and free water. Cold crystallization of water was clearly observed at about −42 °C on heating when the water content was more than 3.0 wt%. Cold crystallization is attributed to the phase transition from the amorphous ice to the crystal ice in PMEA. The relative proportions of freezing-bound water at the EWC is 48 % of all the water in hydrated PMEA. © 2000 Society of Chemical Industry

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