{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360576118819828224.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.cej.2021.133851"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S1385894721054243?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S1385894721054243?httpAccept=text/plain"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Nanoarchitecturing bimetallic manganese cobaltite spinels for sonocatalytic degradation of oxytetracycline"}],"description":[{"notation":[{"@value":"Abstract   Degradation of contaminants of emerging concern in aqueous media using bimetallic oxides is a promising novel strategy that requires engineering new catalytic routes in bimetallic oxides to perform advanced oxidation; however, several challenges to synthesizing and developing such materials with enhanced, sustainable catalytic features are still being investigated. This study presents the effective use of a manganese cobaltite bimetallic spinel structure as a sonocatalyst. We prepared three morphologies of manganese cobaltite for use the sonocatalytic degradation of oxytetracycline (OTC). The morphology of manganese cobaltite is tuned by changing the amounts of the Mn and Co precursors in the early stage of synthesis. Several manganese cobaltite spinels with different structures—porous layered-like cubes (MCO-PLC), layered-like ellipsoids (MCO-LE), and rough spheroids (MCO-RS) were obtained and characterized using various techniques. A promising catalytic degradation capability of MCO-PLC for OTC (10 mg L−1) was obtained at a natural pH within 120 min. We also investigated, the reusability of MCO-PLC sonocatalyst and metal (Mn and Co) leaching in water media. The sonocatalytic mechanisms and fragments produced from OTC during degradation were determined via electron paramagnetic resonance and gas chromatography-mass spectroscopy analyses."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380576118819828242","@type":"Researcher","foaf:name":[{"@value":"Ramin Hassandoost"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828244","@type":"Researcher","foaf:name":[{"@value":"Zahra Movafagh"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828373","@type":"Researcher","foaf:name":[{"@value":"Mohamed Esmat"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828232","@type":"Researcher","foaf:name":[{"@value":"Régis Guegan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828358","@type":"Researcher","foaf:name":[{"@value":"Ahmed Kotb"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828251","@type":"Researcher","foaf:name":[{"@value":"Wipakorn Jevasuwan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828233","@type":"Researcher","foaf:name":[{"@value":"Saki Endo"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828227","@type":"Researcher","foaf:name":[{"@value":"Naoki Fukata"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828378","@type":"Researcher","foaf:name":[{"@value":"Yoshiyuki Sugahara"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828490","@type":"Researcher","foaf:name":[{"@value":"Yusuke Yamauchi"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828384","@type":"Researcher","foaf:name":[{"@value":"Alireza Khataee"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828363","@type":"Researcher","foaf:name":[{"@value":"Yusuke Ide"}]},{"@id":"https://cir.nii.ac.jp/crid/1380576118819828374","@type":"Researcher","foaf:name":[{"@value":"Esmail Doustkhah"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13858947"}],"prism:publicationName":[{"@value":"Chemical Engineering 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BV"}],"prism:publicationDate":"2022-03","prism:volume":"431","prism:startingPage":"133851"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license","http://www.elsevier.com/open-access/userlicense/1.0/","https://doi.org/10.15223/policy-017","https://doi.org/10.15223/policy-037","https://doi.org/10.15223/policy-012","https://doi.org/10.15223/policy-029","https://doi.org/10.15223/policy-004"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S1385894721054243?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S1385894721054243?httpAccept=text/plain"}],"createdAt":"2021-11-26","modifiedAt":"2025-10-24","project":[{"@id":"https://cir.nii.ac.jp/crid/1040851165509765760","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21F20040"},{"@type":"JGN","@value":"JP21F20040"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21F20040/"}],"notation":[{"@language":"ja","@value":"層状チタン酸塩の破裂剥離による多孔質/黒色チタニアナノシート光触媒の創製"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360013170584168960","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Exceptionally 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