{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360579818455000320.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.201802592"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201802592"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201802592"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.201802592"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201802592"}}],"dc:title":[{"@value":"Directional Self‐Assembly and Photoinduced Polymerization of Diacetylene‐Containing Platinum(II) Terpyridine Complexes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A series of newly designed and synthesized diacetylene‐containing platinum(II) terpyridine complexes exhibited intriguing self‐assembly properties. Facilitated by Pt<jats:bold>⋅⋅⋅</jats:bold>Pt, π–π stacking, hydrogen‐bonding and hydrophobic–hydrophobic interactions, these complexes are preorganized to readily undergo topochemical polymerization reactions upon photoirradiation. The in situ polymerization of the diacetylene units to form polydiacetylene, indicated by the UV/Vis spectral changes, gel permeation chromatography and dynamic light scattering, was found to alter their assembly behaviours, as revealed by TEM images.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380579818455000323","@type":"Researcher","foaf:name":[{"@value":"Shishi Fang"}],"jpcoar:affiliationName":[{"@value":"Institute of Molecular Functional Materials, Areas of Excellence Scheme, University Grant Committee (Hong Kong), and Department of Chemistry The University of Hong Kong  Pokfulam Road Hong Kong P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579818455000322","@type":"Researcher","foaf:name":[{"@value":"Sammual Yu‐Lut Leung"}],"jpcoar:affiliationName":[{"@value":"Institute of Molecular Functional Materials, Areas of Excellence Scheme, University Grant Committee (Hong Kong), and Department of Chemistry The University of Hong Kong  Pokfulam Road Hong Kong P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579818455000321","@type":"Researcher","foaf:name":[{"@value":"Yongguang Li"}],"jpcoar:affiliationName":[{"@value":"Institute of Molecular Functional Materials, Areas of Excellence Scheme, University Grant Committee (Hong Kong), and Department of Chemistry The University of Hong Kong  Pokfulam Road Hong Kong P. R. China"},{"@value":"Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510275 P. R. China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579818455000320","@type":"Researcher","foaf:name":[{"@value":"Vivian Wing‐Wah Yam"}],"jpcoar:affiliationName":[{"@value":"Institute of Molecular Functional Materials, Areas of Excellence Scheme, University Grant Committee (Hong Kong), and Department of Chemistry The University of Hong Kong  Pokfulam Road Hong Kong P. R. China"},{"@value":"Lehn Institute of Functional Materials School of Chemistry Sun Yat-Sen University  Guangzhou 510275 P. R. China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2018-09-16","prism:volume":"24","prism:number":"58","prism:startingPage":"15596","prism:endingPage":"15602"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.201802592"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201802592"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.201802592"},{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201802592"}],"createdAt":"2018-09-17","modifiedAt":"2025-10-12","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360306906099911296","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Changes in crystal morphology induced by lanthanide doping into diacetylene lamellar crystals"}]},{"@id":"https://cir.nii.ac.jp/crid/2050025942155222912","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Stimuli-responsive and switchable platinum(Ⅱ) complexes and their applications in memory storage"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/chem.201802592"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220034_references_DOI_305nAoLc7FCcF9mgMQcmMU74STD"},{"@type":"CROSSREF","@value":"10.1038/s41428-024-00917-6_references_DOI_305nAoLc7FCcF9mgMQcmMU74STD"}]}