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However, methods to synthesize highly strained perfluoroarenes are limited, which greatly limits their structural diversity. Herein, we report the synthesis and isolation of perfluorocycloparaphenylenes (PFCPPs) as a class of ring-shaped perfluoroarenes. Using macrocyclic nickel complexes, we succeeded in synthesizing PF[<jats:italic>n</jats:italic>]CPPs (<jats:italic>n</jats:italic> = 10, 12, 14, 16) in one-pot without noble metals. The molecular structures of PF[<jats:italic>n</jats:italic>]CPPs (<jats:italic>n</jats:italic> = 10, 12, 14) were determined by X-ray crystallography to confirm their tubular alignment. Photophysical and electrochemical measurements revealed that PF[<jats:italic>n</jats:italic>]CPPs (<jats:italic>n</jats:italic> = 10, 12, 14) exhibited wide HOMO–LUMO gaps, high reduction potentials, and strong phosphorescence at low temperature. PFCPPs are not only useful as electron-accepting organic materials but can also be used for accelerating the creation of topologically unique molecular nanocarbon materials.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380579819983757700","@type":"Researcher","foaf:name":[{"@value":"Hiroki Shudo"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757702","@type":"Researcher","foaf:name":[{"@value":"Motonobu Kuwayama"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757699","@type":"Researcher","foaf:name":[{"@value":"Masafumi Shimasaki"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757696","@type":"Researcher","foaf:name":[{"@value":"Taishi Nishihara"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757704","@type":"Researcher","foaf:name":[{"@value":"Youhei Takeda"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757698","@type":"Researcher","foaf:name":[{"@value":"Nobuhiko Mitoma"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757705","@type":"Researcher","foaf:name":[{"@value":"Takuya Kuwabara"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757697","@type":"Researcher","foaf:name":[{"@value":"Akiko 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Segawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1380579819983757701","@type":"Researcher","foaf:name":[{"@value":"Kenichiro Itami"}]}],"publication":{"publicationIdentifier":[{"@type":"EISSN","@value":"20411723"}],"prism:publicationName":[{"@value":"Nature Communications"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"2022-06-28","prism:volume":"13","prism:number":"1","prism:startingPage":"3713"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://creativecommons.org/licenses/by/4.0","https://creativecommons.org/licenses/by/4.0"],"url":[{"@id":"https://www.nature.com/articles/s41467-022-31530-x.pdf"},{"@id":"https://www.nature.com/articles/s41467-022-31530-x"}],"createdAt":"2022-06-28","modifiedAt":"2022-11-24","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Science","dc:title":"Science"},{"@id":"https://cir.nii.ac.jp/all?q=Q","dc:title":"Q"},{"@id":"https://cir.nii.ac.jp/all?q=Article","dc:title":"Article"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040014404355192448","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"22KJ1589"},{"@type":"JGN","@value":"JP22KJ1589"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22KJ1589/"}],"notation":[{"@language":"ja","@value":"長尺カーボンナノベルトの化学合成"}]},{"@id":"https://cir.nii.ac.jp/crid/1040855656101007872","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"22K19038"},{"@type":"JGN","@value":"JP22K19038"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22K19038/"}],"notation":[{"@language":"ja","@value":"有機半導体の配向配列問題を解決する3次元πスタック分子の創製"},{"@language":"en","@value":"Creation of 3D pi-stacking system for isotropic organic semiconductors"}]},{"@id":"https://cir.nii.ac.jp/crid/1040862776832472960","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23K23336"},{"@type":"JGN","@value":"JP23K23336"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K23336/"}],"notation":[{"@language":"ja","@value":"トポロジカルπ共役構造体の創製"},{"@language":"en","@value":"Creation of topological pi-conjugated  architectures"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219104833920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Promotion of Reductive Elimination Reaction of Diorgano(2,2′-bipyridyl)nickel(II) Complexes by Electron-Accepting Aromatic Compounds, Lewis Acids, and Brønsted Acids."}]},{"@id":"https://cir.nii.ac.jp/crid/1360004229920546048","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Size‐Selective Complexation 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