{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360580240141804416.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1007/s40820-020-0397-3"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/content/pdf/10.1007/s40820-020-0397-3.pdf"}},{"identifier":{"@type":"URI","@value":"http://link.springer.com/article/10.1007/s40820-020-0397-3/fulltext.html"}}],"dc:title":[{"@value":"Layered Birnessite Cathode with a Displacement/Intercalation Mechanism for High-Performance Aqueous Zinc-Ion Batteries"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Mn-based rechargeable aqueous zinc-ion batteries (ZIBs) are highly promising because of their high operating voltages, attractive energy densities, and eco-friendliness. However, the electrochemical performances of Mn-based cathodes usually suffer from their serious structure transformation upon charge/discharge cycling. Herein, we report a layered sodium-ion/crystal water co-intercalated Birnessite cathode with the formula of Na<jats:sub>0.55</jats:sub>Mn<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>·0.57H<jats:sub>2</jats:sub>O (NMOH) for high-performance aqueous ZIBs. A displacement/intercalation electrochemical mechanism was confirmed in the Mn-based cathode for the first time. Na<jats:sup>+</jats:sup> and crystal water enlarge the interlayer distance to enhance the insertion of Zn<jats:sup>2+</jats:sup>, and some sodium ions are replaced with Zn<jats:sup>2+</jats:sup> in the first cycle to further stabilize the layered structure for subsequent reversible Zn<jats:sup>2+</jats:sup>/H<jats:sup>+</jats:sup> insertion/extraction, resulting in exceptional specific capacities and satisfactory structural stabilities. Additionally, a pseudo-capacitance derived from the surface-adsorbed Na<jats:sup>+</jats:sup> also contributes to the electrochemical performances. The NMOH cathode not only delivers high reversible capacities of 389.8 and 87.1 mA h g<jats:sup>−1</jats:sup> at current densities of 200 and 1500 mA g<jats:sup>−1</jats:sup>, respectively, but also maintains a good long-cycling performance of 201.6 mA h g<jats:sup>−1</jats:sup> at a high current density of 500 mA g<jats:sup>−1</jats:sup> after 400 cycles, which makes the NMOH cathode competitive for practical applications.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380580240141804419","@type":"Researcher","foaf:name":[{"@value":"Xian-Zhi Zhai"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804416","@type":"Researcher","foaf:name":[{"@value":"Jin Qu"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804422","@type":"Researcher","foaf:name":[{"@value":"Shu-Meng Hao"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804421","@type":"Researcher","foaf:name":[{"@value":"Ya-Qiong Jing"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804425","@type":"Researcher","foaf:name":[{"@value":"Wei Chang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804420","@type":"Researcher","foaf:name":[{"@value":"Juan Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804418","@type":"Researcher","foaf:name":[{"@value":"Wei Li"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804423","@type":"Researcher","foaf:name":[{"@value":"Yasmine Abdelkrim"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804417","@type":"Researcher","foaf:name":[{"@value":"Hongfu Yuan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380580240141804424","@type":"Researcher","foaf:name":[{"@value":"Zhong-Zhen Yu"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"23116706"},{"@type":"EISSN","@value":"21505551"}],"prism:publicationName":[{"@value":"Nano-Micro Letters"}],"dc:publisher":[{"@value":"Springer Science and Business Media LLC"}],"prism:publicationDate":"2020-02-18","prism:volume":"12","prism:number":"1","prism:startingPage":"56"},"reviewed":"false","dc:rights":["https://creativecommons.org/licenses/by/4.0","https://creativecommons.org/licenses/by/4.0"],"url":[{"@id":"http://link.springer.com/content/pdf/10.1007/s40820-020-0397-3.pdf"},{"@id":"http://link.springer.com/article/10.1007/s40820-020-0397-3/fulltext.html"}],"createdAt":"2020-02-18","modifiedAt":"2021-02-19","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360298755636472192","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Unveiling the effect of structural water on Zn-ion storage of polyoxovanadate for high-rate and long-life aqueous zinc ion battery"}]},{"@id":"https://cir.nii.ac.jp/crid/1360869855117560832","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Unveiling the Nanoarchitectonics of Interfacial Electronic Coupling in Atomically Thin 2D WO<sub>3</sub>/WSe<sub>2</sub> Heterostructure for Sodium‐Ion Storage in Aqueous System"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1007/s40820-020-0397-3"},{"@type":"CROSSREF","@value":"10.1016/j.cej.2023.142221_references_DOI_YGRcO874v9hreE8fXPM7HWGmb9k"},{"@type":"CROSSREF","@value":"10.1002/adfm.202406333_references_DOI_YGRcO874v9hreE8fXPM7HWGmb9k"}]}