{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360584339749215744.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/ejic.202300663"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.202300663"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Synthesis of 1‐Adamantylaminogermylene and Its Chalcogenation Reactions"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>The synthesis, isolation, and characterization of 1‐adamantylaminogermylene <jats:bold>1</jats:bold> have been achieved utilizing kinetic stabilization with a bulky aryl group on the germanium atom. Aminogermylene <jats:bold>1</jats:bold> was found to be stable in toluene solution at 110 °C for 3 days without decomposition. The chalcogenation reaction of <jats:bold>1</jats:bold> aiming to synthesize heavy amides gave the head‐to‐tail type dimers of the corresponding heavy amides.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380584339749215744","@type":"Researcher","foaf:name":[{"@value":"Mariko Yukimoto"}],"jpcoar:affiliationName":[{"@value":"Institute for Chemical Research Kyoto University  Gokasho 611-0011 Uji Kyoto Japan"},{"@value":"Integrated Research Consortium on Chemical Sciences  Gokasho 611-0011 Uji Kyoto Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380584339749215617","@type":"Researcher","foaf:name":[{"@value":"Kazuaki Kanda"}],"jpcoar:affiliationName":[{"@value":"Institute for Chemical Research Kyoto University  Gokasho 611-0011 Uji Kyoto Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380584339749215619","@type":"Researcher","foaf:name":[{"@value":"Takamasa Aoki"}],"jpcoar:affiliationName":[{"@value":"Institute for Chemical Research Kyoto University  Gokasho 611-0011 Uji Kyoto 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