One-Pot Synthesis of Highly Fluorescent 2,5-Disubstituted-1,3a,6a-triazapentalene

  • Kosuke Namba
    Department of Chemistry, Faculty of Science, Hokkaido University, Kita-ku, Sapporo 060-0810, Japan, and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan
  • Akane Mera
    Department of Chemistry, Faculty of Science, Hokkaido University, Kita-ku, Sapporo 060-0810, Japan, and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan
  • Ayumi Osawa
    Department of Chemistry, Faculty of Science, Hokkaido University, Kita-ku, Sapporo 060-0810, Japan, and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan
  • Eri Sakuda
    Department of Chemistry, Faculty of Science, Hokkaido University, Kita-ku, Sapporo 060-0810, Japan, and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan
  • Noboru Kitamura
    Department of Chemistry, Faculty of Science, Hokkaido University, Kita-ku, Sapporo 060-0810, Japan, and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan
  • Keiji Tanino
    Department of Chemistry, Faculty of Science, Hokkaido University, Kita-ku, Sapporo 060-0810, Japan, and Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo 060-0810, Japan

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説明

A one-pot synthetic method was established for the preparation of 2,5-disubstituted-1,3a,6a-triazapentalenes. The fluorescence observation of the synthetic 2,5-disubstituted-1,3a,6a-triazapentalenes revealed that the introduction of a substituent at the C5 position allowed a substantial change in the fluorescence quantum yield with little effect on the fluorescence wavelength.

収録刊行物

  • Organic Letters

    Organic Letters 14 (21), 5554-5557, 2012-10-16

    American Chemical Society (ACS)

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