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These diene alcohols are oxidized with activated manganese(IV) oxide to give dienones, which are then treated with acid catalysts to undergo ready electrocyclization leading to hexahydroindenones with functional groups. Stereoselectivity at the electrocyclization step is found to depend upon the stereostructures of cyclohexene skeleton of the dienones as well as the reaction conditions.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1582543027620004993","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021885317"}],"foaf:name":[{"@value":"Eiji Wada"}],"jpcoar:affiliationName":[{"@value":"Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326220115584","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40190087"},{"@type":"NRID","@value":"1000040190087"},{"@type":"NRID","@value":"9000256744946"},{"@type":"NRID","@value":"9000345422898"},{"@type":"NRID","@value":"9000257788800"},{"@type":"NRID","@value":"9000257793822"},{"@type":"NRID","@value":"9000021828563"},{"@type":"NRID","@value":"9000257790721"},{"@type":"NRID","@value":"9000004508175"},{"@type":"NRID","@value":"9000252809125"},{"@type":"NRID","@value":"9000009934906"},{"@type":"NRID","@value":"9000004514263"},{"@type":"NRID","@value":"9000021885321"},{"@type":"NRID","@value":"9000257790926"},{"@type":"NRID","@value":"9000015659039"},{"@type":"NRID","@value":"9000283911551"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0017249"}],"foaf:name":[{"@value":"Isamu Fujiwara"}],"jpcoar:affiliationName":[{"@value":"Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University"}]},{"@id":"https://cir.nii.ac.jp/crid/1582543027620004995","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021885324"}],"foaf:name":[{"@value":"Shuji Kanemasa"}],"jpcoar:affiliationName":[{"@value":"Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University"}]},{"@id":"https://cir.nii.ac.jp/crid/1582543027620004992","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000021885328"}],"foaf:name":[{"@value":"Otohiko Tsuge"}],"jpcoar:affiliationName":[{"@value":"Research Institute of Industrial Science, and Department of Molecular Science and Technology, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00092673"},{"@type":"EISSN","@value":"13480634"},{"@type":"PISSN","@value":"09317597"},{"@type":"EISSN","@value":"15222667"}],"prism:publicationName":[{"@value":"Bulletin of the Chemical Society of Japan"}],"dc:publisher":[{"@value":"Oxford University Press (OUP)"}],"prism:publicationDate":"1987-01-01","prism:volume":"60","prism:number":"1","prism:startingPage":"325","prism:endingPage":"334"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["https://academic.oup.com/pages/standard-publication-reuse-rights"],"url":[{"@id":"https://academic.oup.com/bcsj/article-pdf/60/1/325/55722229/bcsj.60.325.pdf"}],"createdAt":"2006-07-26","modifiedAt":"2024-01-18","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011145556606464","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Silanes in organic synthesis. 8. 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Vinyltrimethylsilane, a convenient ethylene equivalent for the synthesis of vinyl arylsulfides, vinyl arylsulfoxides, thiosilylketene acetals, and fused cyclopentenones"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894984214144","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stereocontrolled total synthesis of (±)-Δ9(12)-capnellene"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845133540352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Three-carbon annelations. New routes to the Nazarov cyclization via protected cyanohydrins"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204119975424","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Regio- and stereoselective cyclopentannulation with ketones and propargyl alcohol derivatives. 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