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A Novel Rearrangement of Chromium Allyloxy(aryl)carbene Complexes Catalyzed by Pd(0)
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- Hidehiro Sakurai
- Department of Chemistry, School of Science, The University of Tokyo7-3-1 Hongo, Bunkyo-ku, Tokyo
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- Katsuhiko Tanabe
- Department of Chemistry, School of Science, The University of Tokyo7-3-1 Hongo, Bunkyo-ku, Tokyo
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- Koichi Narasaka
- Department of Chemistry, School of Science, The University of Tokyo7-3-1 Hongo, Bunkyo-ku, Tokyo
Bibliographic Information
- Published
- 1999-01-01
- Rights Information
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/cl.1999.75
- 10.1002/chin.199923060
- Publisher
- Oxford University Press (OUP)
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Description
<jats:title>Abstract</jats:title> <jats:p>Chromium allyloxy(aryl)carbene complexes undergo formal [2,3]- or [1,2]-sigmatropic rearrangement by the catalytic use of Pd(PPh3)4 under CO atmosphere. The reaction is considered to proceed via palladium aroyl π-allyl complex, which is converted to the corresponding aryl ketones by reductive elimination.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 28 (1), 75-76, 1999-01-01
Oxford University Press (OUP)
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Details 詳細情報について
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- CRID
- 1360846644039841664
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- NII Article ID
- 130004421261
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles
- OpenAIRE
