{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360848658121663232.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ic300118d"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ic300118d"}},{"identifier":{"@type":"PMID","@value":"22656193"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Perovskite-to-Postperovskite Transitions in NaNiF<sub>3</sub> and NaCoF<sub>3</sub> and Disproportionation of NaCoF<sub>3</sub> Postperovskite under High Pressure and High Temperature"}],"description":[{"notation":[{"@value":"High-pressure structural phase transitions in NaNiF(3) and NaCoF(3) were investigated by conducting in situ synchrotron powder X-ray diffraction experiments using a diamond anvil cell. The perovskite phases (GdFeO(3) type) started to transform into postperovskite phases (CaIrO(3) type) at about 11-14 GPa, even at room temperature. The transition pressure is much lower than those of oxide perovskites. The anisotropic compression behavior led to heavily tilted octahedra that triggered the transition. Unlike oxide postperovskites, fluoropostperovskites remained after decompression to 1 atm. The postperovskite phase in NaCoF(3) broke down into a mixture of unknown phases after laser heating above 26 GPa, and the phases changed into amorphous ones when the pressure was released. High-pressure and high-temperature experiments using a multianvil apparatus were also conducted to elucidate the phase relations in NaCoF(3). Elemental analysis of the recovered amorphous samples indicated that the NaCoF(3) postperovskite disproportionated into two phases. This kind of disproportionation was not evident in NaNiF(3) even after laser heating at 54 GPa. In contrast to the single postpostperovskite phase reported in NaMgF(3), such a postpostperovskite phase was not found in the present compounds."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801182707712","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"10343865"},{"@type":"NRID","@value":"1000010343865"},{"@type":"ORCID","@value":"0000-0001-6980-9279"},{"@type":"NRID","@value":"9000020752146"},{"@type":"NRID","@value":"9000401968300"},{"@type":"NRID","@value":"9000000789316"},{"@type":"NRID","@value":"9000411369836"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/nimsyusa"}],"foaf:name":[{"@value":"Hitoshi Yusa"}],"jpcoar:affiliationName":[{"@value":"National Institute for Materials Science, 1-1 Namiki, Tsukuba 305-0044,\rJapan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380848658121663105","@type":"Researcher","foaf:name":[{"@value":"Yuichi Shirako"}],"jpcoar:affiliationName":[{"@value":"Department\rof Chemistry, Gakushuin University, 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Hirao"}],"jpcoar:affiliationName":[{"@value":"Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho\r679-5198, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1030285133785205890","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20344400"},{"@type":"NRID","@value":"1000020344400"}],"foaf:name":[{"@value":"Yasuo Ohishi"}],"jpcoar:affiliationName":[{"@value":"Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho\r679-5198, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380848658121663109","@type":"Researcher","foaf:name":[{"@value":"Takumi Kikegawa"}],"jpcoar:affiliationName":[{"@value":"Institute\rof Materials Structure\rScience, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba 305-0801, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00201669"},{"@type":"EISSN","@value":"1520510X"}],"prism:publicationName":[{"@value":"Inorganic Chemistry"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2012-06-01","prism:volume":"51","prism:number":"12","prism:startingPage":"6559","prism:endingPage":"6566"},"reviewed":"false","invited":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ic300118d"}],"createdAt":"2012-06-01","modifiedAt":"2023-04-05","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782100825600","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"22000002"},{"@type":"JGN","@value":"JP22000002"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22000002/"}],"notation":[{"@language":"ja","@value":"地球惑星中心領域の超高圧物質科学"},{"@language":"en","@value":"Ultrahigh-Pressure Material Science of the central regions of the Earth and Planets"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000782109952896","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"22340164"},{"@type":"JGN","@value":"JP22340164"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22340164/"}],"notation":[{"@language":"ja","@value":"超高圧試料の精密揺動技術が拓くその場粉末X線構造解析の新局面"},{"@language":"en","@value":"A new aspect of in-situ powder x-ray diffraction technique by developing the high precision oscillating system for the sample under high pressure"}]},{"@id":"https://cir.nii.ac.jp/crid/1040000782188819200","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24000005"},{"@type":"JGN","@value":"JP24000005"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24000005/"}],"notation":[{"@language":"ja","@value":"地球中心核の物質と進化の解明"},{"@language":"en","@value":"Materials property and evolution of Earth's core"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257086653312","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"22340163"},{"@type":"JGN","@value":"JP22340163"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22340163/"}],"notation":[{"@language":"ja","@value":"マントル鉱物の高圧相平衡と熱力学:ポストスピネルとポストペロブスカイト"},{"@language":"en","@value":"High-pressure phase equilibria and thermodynamics of mantle minerals: postspinel and postperovskite"}]},{"@id":"https://cir.nii.ac.jp/crid/1040282257211022976","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"25106006"},{"@type":"JGN","@value":"JP25106006"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PLANNED-25106006/"}],"notation":[{"@language":"ja","@value":"高圧・高温プロセスを利用した新しい構造―機能相関の探求"},{"@language":"en","@value":"Exploration of co-relation between structure and function for the materials obtained under high pressure and high temperature process"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004232425602688","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"High-pressure transitions in NaZnF3 and NaMnF3 perovskites, and crystal-chemical characteristics of perovskite–postperovskite transitions in ABX3 fluorides and oxides"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011142930365184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Post-Perovskite Phase Transition in MgSiO\n            <sub>3</sub>"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144829138560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Perovskite at high P‐T conditions: An in situ synchrotron X ray diffraction study of NaMgF<sub>3</sub> perovskite"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292617912774528","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Phase 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