{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360848658166184064.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/jp503085f"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/jp503085f"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Origin of Stark Signals Induced by Continuous Photoirradiation for Working Dye-Sensitized Solar Cells Revealed by Photoinduced Absorption Measurements"}],"description":[{"notation":[{"@value":"It has recently been reported that characteristic signals resulting from a Stark effect are included in the spectra of photoinduced absorption (PIA) measurements for dye-sensitized solar cells (DSCs), and the origin of the Stark effect has been discussed in several papers. Here, we explore the origin of the Stark signal observed under continuous photoirradiation from results of continuous wave (cw)-PIA experiments for several control DSCs of ruthenium-based sensitizers (N719). Typical line shape resulting from the Stark effect was observed in the quadrature phase of cw-PIA spectra under short-circuit conditions. The Stark signals are found to arise in relation to stable photocurrent and be independent of the presence of particular electrolyte ions. Time-resolved PIA measurements demonstrate that the Stark signals rise and decay in time scales much slower than the response time of injected electrons in TiO2. We conclude that redox actions of a pair of I–/I3– are responsible for the Stark effect under conti..."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420845751150518272","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40336756"},{"@type":"NRID","@value":"1000040336756"},{"@type":"ORCID","@value":"0000-0001-7437-3940"},{"@type":"NRID","@value":"9000003431604"},{"@type":"NRID","@value":"9000398993597"},{"@type":"NRID","@value":"9000415111974"},{"@type":"NRID","@value":"9000415093699"},{"@type":"NRID","@value":"9000415123907"},{"@type":"NRID","@value":"9000376931239"},{"@type":"NRID","@value":"9000406018032"},{"@type":"NRID","@value":"9000006975647"},{"@type":"NRID","@value":"9000415111409"},{"@type":"NRID","@value":"9000408669234"},{"@type":"NRID","@value":"9000404324810"},{"@type":"NRID","@value":"9000376931067"},{"@type":"NRID","@value":"9000415093713"},{"@type":"NRID","@value":"9000408605720"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0160997"}],"foaf:name":[{"@value":"Katsuichi Kanemoto"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, Graduate School of Science, and ‡The OCU Advanced\rResearch Institute for Natural\rScience and Technology (OCARINA), Osaka City University, 3-3-138\rSugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380848658166183936","@type":"Researcher","foaf:name":[{"@value":"Shinya Domoto"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, Graduate School of Science, and ‡The OCU Advanced\rResearch Institute for Natural\rScience and Technology (OCARINA), Osaka City University, 3-3-138\rSugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380848658166184065","@type":"Researcher","foaf:name":[{"@value":"Hideki Hashimoto"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, Graduate School of Science, and ‡The OCU Advanced\rResearch Institute for Natural\rScience and Technology (OCARINA), Osaka City University, 3-3-138\rSugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"19327447"},{"@type":"EISSN","@value":"19327455"}],"prism:publicationName":[{"@value":"The Journal of Physical Chemistry C"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2014-07-16","prism:volume":"118","prism:number":"31","prism:startingPage":"17260","prism:endingPage":"17265"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/jp503085f"}],"createdAt":"2014-07-08","modifiedAt":"2023-04-23","project":[{"@id":"https://cir.nii.ac.jp/crid/1040000782220835968","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"24656065"},{"@type":"JGN","@value":"JP24656065"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24656065/"}],"notation":[{"@language":"ja","@value":"線形アップコンバージョン発光を利用したエネルギー生成の実現と太陽電池への展開"},{"@language":"en","@value":"Realization of energy generation using linear upconversion luminescence and its developments into solar cells"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011144828093056","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"High Extinction Coefficient “Antenna” Dye in Solid-State Dye-Sensitized Solar Cells: A Photophysical and Electronic Study"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707517547904","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Spectroscopic investigations on Stark components observed in photoinduced absorption measurements for dye-sensitized solar cells"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095418927616","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Simultaneous Transient Absorption and Transient Electrical Measurements on Operating Dye-Sensitized Solar Cells: Elucidating the Intermediates in Iodide 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