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Superexchange mediated energy transfer in zinc(ii) porphyrin–free base porphyrin dimers: comparison of m- and p-bis(phenylethynyl) phenylene linked dimers
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Description
The singlet-singlet energy transfer rate in a new zinc(II) porphyrin-free base porphyrin dimer, having a m-bis(phenylethynyl)phenylene bridge, was found to be slower than that in the corresponding p-bis(phenylethynyl)phenylene-bridged dimer, despite the shorter donor-acceptor distance and pathway. The slower rate is interpreted as evidence for a major contribution of the superexchange mechanism.
Journal
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- Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics 13 (28), 12712-, 2011
Royal Society of Chemistry (RSC)
