{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360855568868422016.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/adfm.200500264"}},{"identifier":{"@type":"URI","@value":"http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.200500264"}},{"identifier":{"@type":"URI","@value":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.200500264"}}],"dc:title":[{"@value":"Self‐Organized Monolayers: A Route to Conformational Switching and Read‐Out of Functional Supramolecular Assemblies by Scanning Probe Methods"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Self‐organized molecular layers provide a promising route to constructing new (switchable) nanodevices and optimizing nanosensors. The design of such molecules involves control of structure and stabilization on the surface, as well as control of functionality. The search for a potentially universal “adapter”, which can control the self‐organization and stabilization on a particular type of surface, is a unique challenge. High‐quality nanoscale imaging using scanning tunneling microscopy (STM) provides the means to further such studies. This article reviews our recent STM work on single molecules, self‐assembled monolayers, and self‐organized monolayers, highlighting our application of a general “self‐organizer” for graphite surfaces, i.e., a Fréchet‐type dendron. How powerfully this self‐organizing motif can affect various central components (catalytic, switchable, redox‐active) on a graphite surface is addressed by analyzing self‐organized monolayers of nine different molecules, each containing at least one first‐ or second‐generation Fréchet‐type dendron. In molecular layers containing a “switchable” core, we can detect a large conformational change upon protonation with HCl gas. Last, but not least, the dynamic surface organization properties of the Fréchet‐type dendrons are described.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380861294502904320","@type":"Researcher","foaf:name":[{"@value":"B. A. Hermann"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861294502904323","@type":"Researcher","foaf:name":[{"@value":"L. J. Scherer"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861294502904321","@type":"Researcher","foaf:name":[{"@value":"C. E. Housecroft"}]},{"@id":"https://cir.nii.ac.jp/crid/1380861294502904322","@type":"Researcher","foaf:name":[{"@value":"E. C. Constable"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"1616301X"},{"@type":"EISSN","@value":"16163028"}],"prism:publicationName":[{"@value":"Advanced Functional Materials"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2006-01-09","prism:volume":"16","prism:number":"2","prism:startingPage":"221","prism:endingPage":"235"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.200500264"},{"@id":"https://advanced.onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.200500264"}],"createdAt":"2006-01-09","modifiedAt":"2025-10-02","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216659209856","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"2D Networks of Rhombic-Shaped Fused Dehydrobenzo[12]annulenes: Structural Variations under Concentration Control"}]},{"@id":"https://cir.nii.ac.jp/crid/1360002216871786496","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Supramolecular surface-confined architectures created by self-assembly of triangular phenylene–ethynylene macrocycles via van der Waals interaction"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691588004608","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Host–Guest Chemistry in Integrated Porous Space Formed by Molecular Self-Assembly at Liquid–Solid Interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183514452096","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Molecular pentagonal tiling: self-assemblies of pentagonal-shaped macrocycles at liquid/solid interfaces"}]},{"@id":"https://cir.nii.ac.jp/crid/1520573329730765568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Award Accounts : The Chemical Society of Japan Award for 2014 : The Chemical Society of Japan Award for Young Chemists for 2011 : Adaptive Building Blocks Consisting of Rigid Triangular Core and Flexible Alkoxy Chains for Self-Assembly at Liquid/Solid Interfaces"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/adfm.200500264"},{"@type":"CROSSREF","@value":"10.1039/c0cc02780d_references_DOI_1Tpc8ZrZ44ipeJRqWpClxIvORPT"},{"@type":"CROSSREF","@value":"10.1021/acs.langmuir.7b00083_references_DOI_1Tpc8ZrZ44ipeJRqWpClxIvORPT"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20160214_references_DOI_1Tpc8ZrZ44ipeJRqWpClxIvORPT"},{"@type":"CROSSREF","@value":"10.1039/c1ce05336a_references_DOI_1Tpc8ZrZ44ipeJRqWpClxIvORPT"},{"@type":"CROSSREF","@value":"10.1021/ja904481j_references_DOI_1Tpc8ZrZ44ipeJRqWpClxIvORPT"}]}