{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360857597134058624.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1039/d1ob01248g"}},{"identifier":{"@type":"URI","@value":"http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01248G"}}],"dc:title":[{"@value":"Cp<sup><i>x</i></sup>M(<scp>iii</scp>)-catalyzed enantioselective C–H functionalization through migratory insertion of metal–carbenes/nitrenes"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>In this review, we highlight the developments in chiral Cp<jats:sup><jats:italic>x</jats:italic></jats:sup>M(<jats:sc>iii</jats:sc>) complexes or achiral Cp<jats:sup><jats:italic>x</jats:italic></jats:sup>M(<jats:sc>iii</jats:sc>) complexes/chiral carboxylic acid-catalyzed enantioselective C–H functionalization reactions through migratory insertion of metal–carbenes/nitrenes.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380857597134058627","@type":"Researcher","foaf:name":[{"@value":"Chongqing Pan"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380857597134058626","@type":"Researcher","foaf:name":[{"@value":"Si-Yong Yin"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380857597134058625","@type":"Researcher","foaf:name":[{"@value":"Qing Gu"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China"}]},{"@id":"https://cir.nii.ac.jp/crid/1380857597134058624","@type":"Researcher","foaf:name":[{"@value":"Shu-Li You"}],"jpcoar:affiliationName":[{"@value":"State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14770520"},{"@type":"EISSN","@value":"14770539"}],"prism:publicationName":[{"@value":"Organic & Biomolecular Chemistry"}],"dc:publisher":[{"@value":"Royal Society of Chemistry (RSC)"}],"prism:publicationDate":"2021","prism:volume":"19","prism:number":"34","prism:startingPage":"7264","prism:endingPage":"7275"},"reviewed":"false","dc:rights":["http://rsc.li/journals-terms-of-use"],"url":[{"@id":"http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01248G"}],"createdAt":"2021-07-28","modifiedAt":"2024-04-17","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050306506450527616","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Cp*Rh-III/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes"},{"@value":"Cp*Rh<sup>III</sup>/Chiral Disulfonate/CuOAc Catalyst System for the Enantioselective Intramolecular Oxyamination of Alkenes"}]},{"@id":"https://cir.nii.ac.jp/crid/1050869456404044800","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Cp*Ir(III)/Chiral Carboxylic Acid-Catalyzed Enantioselective C−H Alkylation of Ferrocene Carboxamides with Diazomalonates"},{"@value":"Cp*Ir(<scp>iii</scp>)/chiral carboxylic acid-catalyzed enantioselective C–H alkylation of ferrocene carboxamides with diazomalonates"}]},{"@id":"https://cir.nii.ac.jp/crid/2050307417131935488","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Enantioselective C-H functionalization using high-valent group 9 metal catalysts"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1039/d1ob01248g"},{"@type":"CROSSREF","@value":"10.1021/acscatal.1c04699_references_DOI_76bGLjgyleeHh8rs9ynMC9TyrzG"},{"@type":"CROSSREF","@value":"10.1039/d1qo01344k_references_DOI_76bGLjgyleeHh8rs9ynMC9TyrzG"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20220168_references_DOI_76bGLjgyleeHh8rs9ynMC9TyrzG"}]}