{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1360865814737870592.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/chem.202303765"}},{"identifier":{"@type":"URI","@value":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202303765"}},{"identifier":{"@type":"PMID","@value":"38088491"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@value":"Neutral Chromium Complex with a Cr≡Si Triple Bond: Synthesis and Photoinduced H−H and Benzene C−H Bond Activation"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>A neutral silylyne complex with a Cr≡Si triple bond was prepared by dehydrogenation of a chromium silylene complex with Cr−H and Si−H bonds, and was isolated as monomeric crystals, unlike dimeric forms of its tungsten and molybdenum congeners. The strong Cr(<jats:italic>δ</jats:italic>−)−Si(<jats:italic>δ</jats:italic>+) bond polarity was revealed by the reaction with MeOH and DFT calculations. The chromium silylyne complex reacted with H<jats:sub>2</jats:sub> under LED (365 nm) irradiation to reproduce the precursor silylene complex with a (H)Cr=Si(H) moiety, as a result of 1,2‐H−H addition across the Cr≡Si triple bond. Similarly, the chromium silylyne complex reacted with benzene under irradiation to afford an 1,2‐addition product with a (H)Cr=Si(Ph) moiety, via benzene C−H bond activation accompanied by Si−C bond forming.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1380865814737870593","@type":"Researcher","foaf:name":[{"@value":"Masahiro Matsuoka"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Graduate School of Science Tohoku University  6-3 Aoba Sendai Miyagi 980–8578 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420001326213303552","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70813830"},{"@type":"NRID","@value":"1000070813830"},{"@type":"NRID","@value":"9000412115312"},{"@type":"NRID","@value":"9000309998805"},{"@type":"NRID","@value":"9000302393201"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/k_nagata"}],"foaf:name":[{"@value":"Koichi Nagata"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Graduate School of Science Tohoku University  6-3 Aoba Sendai Miyagi 980–8578 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380865814737870595","@type":"Researcher","foaf:name":[{"@value":"Ryoma Ohno"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry Faculty of Science and Engineering Kindai University  3-4-1 Kowakae Higashi Osaka, Osaka 577-8502 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420282801202596480","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90312800"},{"@type":"NRID","@value":"1000090312800"},{"@type":"NRID","@value":"9000001132590"},{"@type":"NRID","@value":"9000257715225"},{"@type":"NRID","@value":"9000000306062"},{"@type":"NRID","@value":"9000000638610"},{"@type":"NRID","@value":"9000256019900"},{"@type":"NRID","@value":"9000397946737"},{"@type":"NRID","@value":"9000406227943"},{"@type":"NRID","@value":"9000283122810"},{"@type":"NRID","@value":"9000019111771"},{"@type":"NRID","@value":"9000283393901"},{"@type":"NRID","@value":"9000283124220"},{"@type":"NRID","@value":"9000283124662"},{"@type":"NRID","@value":"9000257708463"},{"@type":"NRID","@value":"9000305637206"},{"@type":"NRID","@value":"9000257711044"},{"@type":"NRID","@value":"9000413380886"},{"@type":"NRID","@value":"9000256017513"},{"@type":"NRID","@value":"9000257738290"},{"@type":"NRID","@value":"9000019058563"},{"@type":"NRID","@value":"9000406560019"},{"@type":"NRID","@value":"9000256018364"},{"@type":"NRID","@value":"9000018923671"},{"@type":"NRID","@value":"9000391396330"},{"@type":"NRID","@value":"9000319050300"},{"@type":"NRID","@value":"9000256028480"},{"@type":"NRID","@value":"9000000842307"},{"@type":"NRID","@value":"9000257708470"},{"@type":"NRID","@value":"9000018731145"},{"@type":"NRID","@value":"9000324995368"},{"@type":"NRID","@value":"9000404109977"},{"@type":"NRID","@value":"9000283124225"},{"@type":"NRID","@value":"9000256016556"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/tsukasamatsuo"}],"foaf:name":[{"@value":"Tsukasa Matsuo"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry Faculty of Science and Engineering Kindai University  3-4-1 Kowakae Higashi Osaka, Osaka 577-8502 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1380865814737870594","@type":"Researcher","foaf:name":[{"@value":"Hiromi Tobita"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Graduate School of Science Tohoku University  6-3 Aoba Sendai Miyagi 980–8578 Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751163782400","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"60291085"},{"@type":"NRID","@value":"1000060291085"},{"@type":"NRID","@value":"9000001962911"},{"@type":"NRID","@value":"9000412115311"},{"@type":"NRID","@value":"9000257722864"},{"@type":"NRID","@value":"9000257730362"},{"@type":"NRID","@value":"9000000262150"},{"@type":"NRID","@value":"9000000259712"},{"@type":"NRID","@value":"9000257710952"},{"@type":"NRID","@value":"9000001128032"},{"@type":"NRID","@value":"9000410658042"},{"@type":"NRID","@value":"9000000873665"},{"@type":"NRID","@value":"9000018232380"},{"@type":"NRID","@value":"9000406560016"},{"@type":"NRID","@value":"9000257714580"},{"@type":"NRID","@value":"9000018507808"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0055405"}],"foaf:name":[{"@value":"Hisako Hashimoto"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Graduate School of Science Tohoku University  6-3 Aoba Sendai Miyagi 980–8578 Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09476539"},{"@type":"EISSN","@value":"15213765"}],"prism:publicationName":[{"@value":"Chemistry – A European Journal"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2023-12-22","prism:volume":"30","prism:number":"9"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","dc:rights":["http://creativecommons.org/licenses/by-nc-nd/4.0/"],"url":[{"@id":"https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202303765"}],"createdAt":"2023-12-13","modifiedAt":"2025-10-12","project":[{"@id":"https://cir.nii.ac.jp/crid/1040569382215923200","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21K14638"},{"@type":"JGN","@value":"JP21K14638"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K14638/"}],"notation":[{"@language":"ja","@value":"複合アニオン型POM錯体の新規合成法の確立と固体触媒への展開"},{"@language":"en","@value":"Establishment of a New Synthetic Method for Mixed-Anionic POM Complexes and Its Application toward Solid State Catalysts"}]},{"@id":"https://cir.nii.ac.jp/crid/1040569382221038592","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"21K05091"},{"@type":"JGN","@value":"JP21K05091"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21K05091/"}],"notation":[{"@language":"ja","@value":"高度に分極した高周期１４族元素－炭素多重結合化学種の合成と反応性の探究"},{"@language":"en","@value":"Synthesis and reactivity of heavier group 14 elements-carbon multiple-bond species with a highly polarized structure"}]},{"@id":"https://cir.nii.ac.jp/crid/1040862776832481152","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"23K23356"},{"@type":"JGN","@value":"JP23K23356"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23K23356/"}],"notation":[{"@language":"ja","@value":"低原子価の13・14族高周期元素ー金属結合の協働作用を鍵とする高活性反応場の創製"},{"@language":"en","@value":"Low-valent, heavy Group 13 and Group 14 elements: Creation of highly active reaction fields driven by synergistic effects with metal bonds"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002219096876288","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent Developments in the Reactivity of Stable Disilynes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004232308507392","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"NHC-induced conversion of a W–Ge double bond into the triple bond through formation of W–Ge single and double bonded intermediates"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233213712128","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reactions of a Tungsten–Germylyne Complex with α,β-Unsaturated Ketones: Complete Cleavage of the W≡Ge Bond and Formation of Two Types of η<sup>3</sup>-Germoxyallyl Tungsten Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011143829051136","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011144459623680","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ<sup>3</sup>-tmps)(CO)<sub>2</sub>NbE–R] (E = Si, Ge, Sn; tmps = MeSi(CH<sub>2</sub>PMe<sub>2</sub>)<sub>3</sub>; R = aryl)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017280664986368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Photoinduced One-Pot Synthesis of a Chromium Germylyne Complex and Its Formation Mechanism"}]},{"@id":"https://cir.nii.ac.jp/crid/1360017286006887808","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Transition metal chemistry of heavier group 14 congener triple-bonded complexes: syntheses and reactivity"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021390565440640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Π‐Character of Chromium Germylyne Complex in the Reactions with Enone, Butadiene, and Alkynes: Formation of Germacycles through [2+4] Cycloaddition with Conjugated Molecules"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021393779048192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cationic Tetrylene‐Iron(0) Complexes: Access Points for Cooperative, Reversible Bond Activation and Open‐Shell Iron(−I) Ferrato‐Tetrylenes**"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021393779869696","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Germyl- and Germylene-Bridged Complexes of Rh/Ir and Subsequent Chemistry of a Bridging Germylene Group"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021393780825216","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Electronic Nature of Cationic Group 10 Ylidyne Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021395464689152","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Versatile Fe–Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C–H Bond Activation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021395464857344","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Small molecule activation by well-defined compounds of heavy p-block elements"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021396131313792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis of Cobalt‐Tin and ‐Lead Tetrylidynes—Reactivity Study of the Triple Bond"}]},{"@id":"https://cir.nii.ac.jp/crid/1360021396131971712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"C–H and H–H Bond Activation by a Cationic Germylyne Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694082185216","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Highly Coplanar (<i>E</i>)-1,2-Di(1-naphthyl)disilene Involving a Distinct CH–π Interaction with the Perpendicularly Oriented Protecting Eind Group"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285708117894016","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"A Silylyne Tungsten Complex Having an Eind Group on Silicon: Its Dimer–Monomer Equilibrium and Cycloaddition Reactions with Carbodiimide and Diaryl Ketones"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292618838233600","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Formation of a Germylyne Complex: Dehydrogenation of a Hydrido(hydrogermylene)tungsten Complex with Mesityl Isocyanate"}]},{"@id":"https://cir.nii.ac.jp/crid/1360292620321539712","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Main-group elements as transition metals"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298761964393472","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cooperativity in Transition Metal Tetrylene Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302869432533504","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reversible metathesis of ammonia in an acyclic germylene–Ni<sup>0</sup> complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360302869432537728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH<sub>3</sub>, N<sub>2</sub>H<sub>4</sub>, H<sub>2</sub>O, H<sub>2</sub>)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169050241024","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis and Structures of a Series of Bulky “Rind-Br” Based on a Rigid Fused-Ring <i>s</i>-Hydrindacene Skeleton"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183519300352","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093892462976","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Silylene–Nickel Promoted Cleavage of B−O Bonds: From Catechol Borane to the Hydroborylene Ligand"}]},{"@id":"https://cir.nii.ac.jp/crid/1360580237019795968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me<sub>3</sub>P)<sub>2</sub>(Ph<sub>3</sub>P)Rh≡E‐Ar*] (E=Sn, Pb)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848654927166592","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reactions of a Silylyne Complex with Aldehydes: Formation of W−Si−O−C Four‐Membered Metallacycles and Their Metathesis‐Like Fragmentation"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848656970397056","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Recent advances in the chemistry of transition metal–silicon/germanium triple-bonded complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658071240320","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis of a Tungsten–Silylyne Complex via Stepwise Proton and Hydride Abstraction from a Hydrido Hydrosilylene Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569357200768","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Osmium–Silicon Triple Bond: Synthesis, Characterization, and Reactivity of an Osmium Silylyne Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855570171065984","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal–Silicon Triple Bonds: Access to [Si(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)]<sup>+</sup> from SiX<sub>2</sub>(NHC) and its Conversion to the Silylidyne Complex [Tp<sup>Me</sup>(CO)<sub>2</sub>MoSi(η<sup>3</sup>-C<sub>5</sub>Me<sub>5</sub>)] (Tp<sup>Me</sup> = κ<sup>3</sup>-<i>N</i>,<i>N</i>′,<i>N</i>″-hydridotris(3,5-dimethyl-1-pyrazolyl)borate)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855571472596864","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Multiple Bonding Between Silicon and Molybdenum: A Transition‐Metal Complex with Considerable Silylyne Character"}]},{"@id":"https://cir.nii.ac.jp/crid/1360857692581391488","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The continuum of carbon–hydrogen (C–H) activation mechanisms and terminology"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865816796536320","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Neutral Silylyne Complex of Molybdenum: Synthesis, Properties, and Access to Silaiminoacyl Complexes via [2+3] Cycloaddition"}]},{"@id":"https://cir.nii.ac.jp/crid/1360865820394995968","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Reversible Insertion Reactions of a Platinum Germylene Complex"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137043809220992","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synthesis of a Molybdenum Hydrido(hydrogermylene) Complex and Its Conversion to a Germylyne Complex: Another Route through Dehydrogenation with Nitriles"}]},{"@id":"https://cir.nii.ac.jp/crid/1361137043827414656","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"η2 Coordination of Si–H σ Bonds to Transition Metals"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420188984064","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal–Silicon Triple Bonds: The Molybdenum Silylidyne Complex [Cp(CO)<sub>2</sub>Mo≡Si‐R]"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825893957227648","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Cleavage of Si–H, B–H, and C–H Bonds by Metal–Ligand Cooperation"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825894385020416","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Understanding and exploiting C–H bond activation"}]},{"@id":"https://cir.nii.ac.jp/crid/1362825895618491904","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Coplanar Oligo(<i>p</i>-phenylenedisilenylene)s Based on the Octaethyl-Substituted <i>s</i>-Hydrindacenyl Groups"}]},{"@id":"https://cir.nii.ac.jp/crid/1363107370420410112","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Linearly Two-Coordinated Silicon: Transition Metal Complexes with the Functional Groups M≡Si—M and M═Si═M"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845594269568","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Silicon–Oxygen Double Bonds: A Stable Silanone with a Trigonal‐Planar Coordinated Silicon Center"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670321159221120","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Metal–Silicon Triple Bonds: Nucleophilic Addition and Redox Reactions of the Silylidyne Complex [Cp(CO)<sub>2</sub>MoSi‐R]"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951793399268864","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Methane activation and exchange by titanium-carbon multiple bonds"}]},{"@id":"https://cir.nii.ac.jp/crid/1363951795900375168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Stable singlet carbenes as mimics for transition metal centers"}]},{"@id":"https://cir.nii.ac.jp/crid/1880303266599393152","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 2291641: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1880584741596860928","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 2291646: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1883399491337173504","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 2291649: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1883962441302305536","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 2291643: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1883962441310425984","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 2291645: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/2051714792011536128","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Transition-metal complexes with triple bonds to Si, Ge, Sn, and Pb and relevant complexes"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/chem.202303765"},{"@type":"KAKEN","@value":"PRODUCT-24792889"},{"@type":"KAKEN","@value":"PRODUCT-25014888"},{"@type":"KAKEN","@value":"PRODUCT-25552905"},{"@type":"KAKEN","@value":"PRODUCT-25369494"},{"@type":"OPENAIRE","@value":"doi_dedup___::c27046140a1f02d568c7d782cd77e35d"}]}