{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137043473162368.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/anie.201811037"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201811037"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201811037"}},{"identifier":{"@type":"URI","@value":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201811037"}}],"dc:title":[{"@value":"Hydrophobic Shielding of Outer Surface: Enhancing the Chemical Stability of Metal–Organic Polyhedra"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Metal–organic polyhedra (MOP) are a promising class of crystalline porous materials with multifarious potential applications. Although MOPs and metal–organic frameworks (MOFs) have similar potential in terms of their intrinsic porosities and physicochemical properties, the exploitation of carboxylate MOPs is still rudimentary because of the lack of systematic development addressing their chemical stability. Herein we describe the fabrication of chemically robust carboxylate MOPs via outer‐surface functionalization as an a priori methodology, to stabilize those MOPs system where metal–ligand bond is not so strong. Fine‐tuning of hydrophobic shielding is key to attaining chemical inertness with retention of the framework integrity over a wide range of pH values, in strong acidic conditions, and in oxidizing and reducing media. These results are further corroborated by molecular modelling studies. Owing to the unprecedented transition from instability to a chemically ultra‐stable regime using a rapid ambient‐temperature gram‐scale synthesis (within seconds), a prototype strategy towards chemically stable MOPs is reported.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137043473162372","@type":"Researcher","foaf:name":[{"@value":"Samraj Mollick"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Indian Institute, of Science Education and Research (IISER)  Pune India"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162377","@type":"Researcher","foaf:name":[{"@value":"Soumya Mukherjee"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Indian Institute, of Science Education and Research (IISER)  Pune India"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162369","@type":"Researcher","foaf:name":[{"@value":"Dongwook Kim"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Ulsan National Institute, of Science and Technology (UNIST)  Ulsan 44918 Korea"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162373","@type":"Researcher","foaf:name":[{"@value":"Zhiwei Qiao"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical and Biomolecular Engineering National University of Singapore  117576 Singapore Singapore"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162368","@type":"Researcher","foaf:name":[{"@value":"Aamod V. Desai"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Indian Institute, of Science Education and Research (IISER)  Pune India"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162375","@type":"Researcher","foaf:name":[{"@value":"Rajat Saha"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Kazi Nazrul University  Kalla Asansol 713340 India"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162374","@type":"Researcher","foaf:name":[{"@value":"Yogeshwar D. More"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Indian Institute, of Science Education and Research (IISER)  Pune India"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162376","@type":"Researcher","foaf:name":[{"@value":"Jianwen Jiang"}],"jpcoar:affiliationName":[{"@value":"Department of Chemical and Biomolecular Engineering National University of Singapore  117576 Singapore Singapore"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162370","@type":"Researcher","foaf:name":[{"@value":"Myoung Soo Lah"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Ulsan National Institute, of Science and Technology (UNIST)  Ulsan 44918 Korea"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137043473162371","@type":"Researcher","foaf:name":[{"@value":"Sujit K. Ghosh"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry Indian Institute, of Science Education and Research (IISER)  Pune India"},{"@value":"Centre for Energy Science IISER Pune  Pune 411008 India"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"14337851"},{"@type":"EISSN","@value":"15213773"}],"prism:publicationName":[{"@value":"Angewandte Chemie International Edition"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2019-01-02","prism:volume":"58","prism:number":"4","prism:startingPage":"1041","prism:endingPage":"1045"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201811037"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201811037"},{"@id":"https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201811037"}],"createdAt":"2018-12-04","modifiedAt":"2023-09-11","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360294643864823680","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Porous Colloidal Hydrogels Formed by Coordination‐Driven Self‐Assembly of Charged Metal‐Organic Polyhedra"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298345008350720","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Coordination/metal–organic cages inside out"}]},{"@id":"https://cir.nii.ac.jp/crid/1360584340519101440","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Water-Soluble Ionic Metal–Organic Polyhedra as a Versatile Platform for Enzyme Bio-immobilization"}]},{"@id":"https://cir.nii.ac.jp/crid/1361975843352442368","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing"}]},{"@id":"https://cir.nii.ac.jp/crid/2050588892102334592","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Metal-organic cages (MOCs) : from discrete to cage-based extended architectures"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1002/anie.201811037"},{"@type":"CROSSREF","@value":"10.1016/j.ccr.2022.214612_references_DOI_8g4brLjvXp1209qodLycm1AqVZD"},{"@type":"CROSSREF","@value":"10.1246/cl.190731_references_DOI_8g4brLjvXp1209qodLycm1AqVZD"},{"@type":"CROSSREF","@value":"10.1002/asia.202100080_references_DOI_8g4brLjvXp1209qodLycm1AqVZD"},{"@type":"CROSSREF","@value":"10.1021/jacs.2c13798_references_DOI_8g4brLjvXp1209qodLycm1AqVZD"},{"@type":"CROSSREF","@value":"10.1039/d0cc00932f_references_DOI_8g4brLjvXp1209qodLycm1AqVZD"}]}