{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137044032055424.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1029/jb095ib13p21737"}},{"identifier":{"@type":"URI","@value":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1029%2FJB095iB13p21737"}},{"identifier":{"@type":"URI","@value":"https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/JB095iB13p21737"}},{"identifier":{"@type":"NAID","@value":"80005665229"}}],"dc:title":[{"@value":"Static compression of iron to 300 GPa and Fe<sub>0.8</sub>Ni<sub>0.2</sub> alloy to 260 GPa: Implications for composition of the core"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>We report the results of X ray diffraction experiments with the diamond anvil cell to pressures above 300 GPa at room temperature on pure iron and an iron‐nickel alloy. These data extend throughout the pressure range of the bulk of the outer core of the Earth and provide for the first time direct pressure‐volume measurements on geophysically important materials at such conditions. Both iron and iron‐nickel are observed to remain in the hexagonal close‐packed structure to the maximum pressures. A combined fit to all recent compression data up to 300 GPa gives the following Birch‐Murnaghan equation‐of‐state (EOS) parameters for iron: <jats:italic>V</jats:italic><jats:sub>02</jats:sub> = 6.73(1) cm<jats:sup>3</jats:sup> mol<jats:sup>−1</jats:sup>, <jats:italic>K</jats:italic><jats:sub>02</jats:sub> = 165(4) GPa, and <jats:italic>K</jats:italic>′<jats:sub>02</jats:sub> = 5.33(9). (Value in parentheses refers to the uncertainty of the last digit; e.g., 6.73(1) refers to 6.73+0.01.). Similar parameters are obtained with a recent “universal” form of the EOS of solids. For an Fe<jats:sub>0.8</jats:sub> Ni<jats:sub>0.2</jats:sub> alloy, the equation‐of‐state parameters are nearly identical, within error: <jats:italic>V</jats:italic><jats:sub>02</jats:sub> = 6.737(5) cm<jats:sup>3</jats:sup> mol<jats:sup>−1</jats:sup>, <jats:italic>K</jats:italic><jats:sub>02</jats:sub> = 172(2) GPa, and <jats:italic>K</jats:italic>′<jats:sub>02</jats:sub> = 4.95(9). In terms of volume, the alloy equation‐of‐state is indistinguishable from that of pure iron and the densities differ (dominantly in proportion to their atomic weights) by ∼0.3 Mg m<jats:sup>−3</jats:sup> at 330 GPa. Within the range of uncertainty in Earth model densities and trade‐offs with the percentage light component in the core, nickel could be present in the core in an amount at least equal to its estimated abundance in the Earth. A direct comparison with (solid) inner core densities is now possible and places direct constraints on the thermal models of the Earth's interior.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1581417126636627968","@type":"Researcher","foaf:name":[{"@value":"H. K. Mao"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044032055425","@type":"Researcher","foaf:name":[{"@value":"Y. Wu"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044032055427","@type":"Researcher","foaf:name":[{"@value":"L. C. Chen"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044032055424","@type":"Researcher","foaf:name":[{"@value":"J. F. Shu"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044032055428","@type":"Researcher","foaf:name":[{"@value":"Andrew P. Jephcoat"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"01480227"},{"@type":"PISSN","@value":"http://id.crossref.org/issn/01480227"}],"prism:publicationName":[{"@value":"Journal of Geophysical Research: Solid Earth"}],"dc:publisher":[{"@value":"American Geophysical Union (AGU)"}],"prism:publicationDate":"1990-12-10","prism:volume":"95","prism:number":"B13","prism:startingPage":"21737","prism:endingPage":"21742"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1029%2FJB095iB13p21737"},{"@id":"https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/JB095iB13p21737"}],"createdAt":"2008-02-06","modifiedAt":"2023-09-22","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1050018218946822272","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Development of an 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Properties of Close-Packed Fe at High Pressures (1st Report, Derivation of Classical Thermodynamic Relations)"},{"@value":"高圧でのちゅう密鉄の熱物性に関する研究（第１報，古典熱力学パラメーター間の関係式の導出とその応用）"},{"@language":"ja-Kana","@value":"コウアツ デ ノ チュウミツテツ ノ ネツ ブッセイ ニ カンスル ケンキュウ ダイ1ポウ コテン ネツリキガク パラメーター カン ノ カンケイシキ ノ ドウシュツ ト ソノ オウヨウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206545741440","@type":"Article","relationType":["isReferencedBy","isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Application of FIB system to ultra-high-pressure Earth science"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679357310464","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"High Brilliance and High Pressure: A New Diamond Anvil Cell Facility at the Advanced Photon Source."},{"@language":"ja-Kana","@value":"High Brilliance and High Pressure A New"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679357444608","@type":"Article","resourceType":"学術雑誌論文(journal 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メザシテ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679358484480","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrical Resistance Measurement Techniques for Metal Hydrides under High-Pressure H2 Conditions & Electrical Transport and Structural Properties of FeHx"},{"@language":"ja","@value":"高圧水素中における金属水素化物の電気抵抗測定技術及び鉄水素化物の電気伝導特性と結晶構造"},{"@language":"ja-Kana","@value":"コウアツ スイソ チュウ ニ オケル キンゾク スイソカブツ ノ デンキ テイコウ ソクテイ ギジュツ オヨビ テツ スイソカブツ ノ デンキ デンドウ トクセイ ト ケッショウ コウゾウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679454374016","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Thermal Properties of Close-Packed Fe at High Pressures (2nd Report, Efficacy of Hugoniot Temperatures, Constant-volume Specific Heats, and Grueneisen Coefficients)"},{"@value":"高圧でのちゅう密鉄の熱物性に関する研究（第２報，ユゴニオ温度，定積比熱，グリュナイゼン係数の有効性）"},{"@language":"ja-Kana","@value":"コウアツ デ ノ チュウミツテツ ノ ネツ ブッセイ ニ カンスル ケンキュウ ダイ2ホウ ユゴニオ 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