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X‐ray crystallography not only confirmed the molecular structure of Li<jats:sup>+</jats:sup>@C<jats:sub>60</jats:sub>⊂[10]CPP⋅X<jats:sup>−</jats:sup> but also uncovered the formation of a unique ionic crystal. The strong charge‐transfer interaction between [10]CPP and Li<jats:sup>+</jats:sup>@C<jats:sub>60</jats:sub>, which was confirmed by electrochemical measurement and spectroscopic analyses, caused significant delocalization of the positive charge across the entire complex.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137044168311682","@type":"Researcher","foaf:name":[{"@value":"Hiroshi Ueno"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044168311680","@type":"Researcher","foaf:name":[{"@value":"Taishi Nishihara"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044168311683","@type":"Researcher","foaf:name":[{"@value":"Yasutomo Segawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044168311681","@type":"Researcher","foaf:name":[{"@value":"Kenichiro 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Chemie"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2015-02-18","prism:volume":"127","prism:number":"12","prism:startingPage":"3778","prism:endingPage":"3782"},"reviewed":"false","dc:rights":["http://onlinelibrary.wiley.com/termsAndConditions#vor"],"url":[{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201500544"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201500544"},{"@id":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201500544"},{"@id":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201500544"}],"createdAt":"2015-02-18","modifiedAt":"2023-10-16","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Ions","dc:title":"Ions"},{"@id":"https://cir.nii.ac.jp/all?q=Molecular%20Conformation","dc:title":"Molecular Conformation"},{"@id":"https://cir.nii.ac.jp/all?q=Cycloparaffins","dc:title":"Cycloparaffins"},{"@id":"https://cir.nii.ac.jp/all?q=Electrochemical%20Techniques","dc:title":"Electrochemical 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