Formation of gold-like metal-lustrous inclusion crystals from 1-phenyl-2,5-bis[5-(tricyanoethenyl)-2-thienyl]pyrrole host and an electron-donating aromatic guest
書誌事項
- 公開日
- 2003
- DOI
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- 10.1039/b302689b
- 公開者
- Royal Society of Chemistry (RSC)
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説明
A novel pi-conjugated organic compound, 1-phenyl-2,5-bis[5-(tricyanoethenyl)-2-thienyl]pyrrole, which bears two powerful electron-withdrawing tricyanoethenyl substitutents, readily yielded gold-like metal-lustrous inclusion crystals with a series of aromatic guest molecules such as toluene, p-xylene, anisole, dimethoxybenzenes and indene. All the inclusion compounds have a common stoichiometric ratio (host/guest) of 2 : 1. X-Ray structural analyses demonstrate that the structural feature for toluene included crystal is similar to those containing p-xylene, anisole, dimethoxybenzenes and indene.
収録刊行物
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- Organic & Biomolecular Chemistry
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Organic & Biomolecular Chemistry 1 (21), 3845-, 2003
Royal Society of Chemistry (RSC)
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詳細情報 詳細情報について
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- CRID
- 1361137044204207232
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- DOI
- 10.1039/b302689b
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- ISSN
- 14770539
- 14770520
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- PubMed
- 14649917
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- データソース種別
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- Crossref
- OpenAIRE
