{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137044385703552.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1063/1.4793999"}},{"identifier":{"@type":"URI","@value":"https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.4793999/14279527/091604_1_online.pdf"}}],"dc:title":[{"@value":"Work function and electron affinity of the fluorine-terminated (100) diamond surface"}],"description":[{"type":"abstract","notation":[{"@value":"<jats:p>The work function and electron affinity of fluorine-terminated (100) diamond surfaces prepared by exposure to dissociated XeF2 have been determined using synchrotron-based photoemission. After vacuum annealing to 350 °C a clean, monofluoride terminated C(100):F surface was obtained for which an electron affinity of 2.56 eV was measured. This is the highest electron affinity reported for any diamond surface termination so far, and it exceeds the value predicted by recent density functional theory calculations by 0.43 eV. The work function of 7.24 eV measured for the same surface places the Fermi energy of 0.79 eV above the valence band maximum.</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137044385703553","@type":"Researcher","foaf:name":[{"@value":"K. J. Rietwyk"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, La Trobe University 1 , Victoria 3086, Australia"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044385703552","@type":"Researcher","foaf:name":[{"@value":"S. L. Wong"}],"jpcoar:affiliationName":[{"@value":"NUS Graduate School of Integrative Sciences and Engineering, National University of Singapore 2 , 28Medical Drive S117456, Singapore"},{"@value":"Department of Physics, National University of Singapore 3 , Singapore 117542, Singapore"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044385703556","@type":"Researcher","foaf:name":[{"@value":"L. Cao"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, National University of Singapore 4 , 3 Science Drive, Singapore 117543, Singapore"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044385703558","@type":"Researcher","foaf:name":[{"@value":"K. M. O'Donnell"}],"jpcoar:affiliationName":[{"@value":"Australian Synchrotron 5 , 800 Blackburn Road, Clayton, Victoria 3168, Australia"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044385703557","@type":"Researcher","foaf:name":[{"@value":"L. Ley"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, La Trobe University 1 , Victoria 3086, Australia"},{"@value":"Institut für Technische Physik, Universität Erlangen 6 , Erwin-Rommel-Str. 1, 91058 Erlangen, Germany"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044385703554","@type":"Researcher","foaf:name":[{"@value":"A. T. S. Wee"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, National University of Singapore 3 , Singapore 117542, Singapore"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044385703555","@type":"Researcher","foaf:name":[{"@value":"C. I. Pakes"}],"jpcoar:affiliationName":[{"@value":"Department of Physics, La Trobe University 1 , Victoria 3086, Australia"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00036951"},{"@type":"EISSN","@value":"10773118"}],"prism:publicationName":[{"@value":"Applied Physics Letters"}],"dc:publisher":[{"@value":"AIP Publishing"}],"prism:publicationDate":"2013-03-04","prism:volume":"102","prism:number":"9","prism:startingPage":"091604"},"reviewed":"false","url":[{"@id":"https://pubs.aip.org/aip/apl/article-pdf/doi/10.1063/1.4793999/14279527/091604_1_online.pdf"}],"createdAt":"2013-03-08","modifiedAt":"2024-05-07","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004234424205952","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Microfabrication of a scanning probe with NV centers in a selectively grown diamond thin film through a xenon difluoride etching process"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183088857984","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Nitrogen-Terminated Diamond Surface for Nanoscale NMR by Shallow Nitrogen-Vacancy Centers"}]},{"@id":"https://cir.nii.ac.jp/crid/1360853567513381632","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electrochemical properties of fluorinated boron-doped diamond electrodes<i>via</i>fluorine-containing plasma treatment"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1063/1.4793999"},{"@type":"CROSSREF","@value":"10.1088/1361-6439/aa8f12_references_DOI_RXx7bHRQfiv7utvqGLBIi0q3zo"},{"@type":"CROSSREF","@value":"10.1021/acs.jpcc.8b11274_references_DOI_RXx7bHRQfiv7utvqGLBIi0q3zo"},{"@type":"CROSSREF","@value":"10.1039/c8cp07402j_references_DOI_RXx7bHRQfiv7utvqGLBIi0q3zo"}]}