{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137044594433408.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja00504a052"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja00504a052"}}],"dc:title":[{"@value":"Aliphatic Claisen rearrangement transition state structure from secondary .alpha.-deuterium isotope effects"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137044594433409","@type":"Researcher","foaf:name":[{"@value":"J. J. Gajewski"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044594433408","@type":"Researcher","foaf:name":[{"@value":"N. D. Conrad"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"1979-05","prism:volume":"101","prism:number":"10","prism:startingPage":"2747","prism:endingPage":"2748"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja00504a052"}],"createdAt":"2005-03-18","modifiedAt":"2023-03-30","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283694088118784","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Direct Observation of the Molecular Structural Changes during the Claisen Rearrangement Including the Transition State"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848662308979584","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A new reaction mechanism of Claisen rearrangement induced by few-optical-cycle pulses: Demonstration of nonthermal chemistry by femtosecond vibrational spectroscopy"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848664436890624","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The Reaction Mechanism of Claisen Rearrangement  Obtained by Transition State Spectroscopy and Single  Direct-Dynamics Trajectory"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680210033152","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"遷移状態を含む光反応・熱反応過程の直接観測に基づく反応機構解明"},{"@language":"en","@value":"Analysis of Reaction Mechanisms based on Direct Observation of the Molecular Structual Changes during both Poto- and Thermal Reactions including the Transition States"},{"@language":"ja-Kana","@value":"センイ ジョウタイ オ フクム ヒカリ ハンノウ ・ ネツ ハンノウ カテイ ノ チョクセツ カンソク ニ モトズク ハンノウ キコウ カイメイ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681266829696","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Synthesis of New Organic Crosslinking Reagents Containing SiH Bonds and Curing System Thereof."}]},{"@id":"https://cir.nii.ac.jp/crid/1521980704682237440","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Award Accounts : The Chemical Society of Japan Award for Young Chemists for 2014 : Development of Novel Reactions Induced by Coherent Molecular Vibrational Excitation and Direct Observation of Molecular Structural Change during \"Thermal\" Reactions"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/ja00504a052"},{"@type":"CROSSREF","@value":"10.1295/polymj.25.379_references_DOI_CdfdoECU1U226j4ee98Z6DDi5eP"},{"@type":"CROSSREF","@value":"10.5939/sjws.16003_references_DOI_CdfdoECU1U226j4ee98Z6DDi5eP"},{"@type":"CROSSREF","@value":"10.3390/molecules18021995_references_DOI_CdfdoECU1U226j4ee98Z6DDi5eP"},{"@type":"CROSSREF","@value":"10.1351/pac-con-12-12-01_references_DOI_CdfdoECU1U226j4ee98Z6DDi5eP"},{"@type":"CROSSREF","@value":"10.1246/cl.2010.374_references_DOI_CdfdoECU1U226j4ee98Z6DDi5eP"},{"@type":"CROSSREF","@value":"10.1246/bcsj.20150242_references_DOI_CdfdoECU1U226j4ee98Z6DDi5eP"}]}