{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137044963666048.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ja062399i"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/ja062399i"}},{"identifier":{"@type":"PMID","@value":"16834354"}},{"identifier":{"@type":"NAID","@value":"30011177311"}}],"dc:title":[{"@value":"A Binuclear Fe(III)Dy(III) Single Molecule Magnet. Quantum Effects and Models"}],"description":[{"notation":[{"@value":"The binuclear [FeIII(bpca)(mu-bpca)Dy(NO3)4], having Single Molecule Magnet (SMM) properties, belonging to a series of isostructural FeIIILnIII complexes (Ln = Eu, Gd, Tb, Dy, Ho) and closely related FeIILnIII chain structures, was characterized in concise experimental and theoretical respects. The low temperature magnetization data showed hysteresis and tunneling. The anomalous temperature dependence of Mössbauer spectra is related to the onset of magnetic order, consistent with the magnetization relaxation time scale resulting from AC susceptibility measurements. The advanced ab initio calculations (CASSCF and spin-orbit) revealed the interplay of ligand field, spin-orbit, and exchange effects and probed the effective Ising nature of the lowest states, involved in the SMM and tunneling effects."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137044963666055","@type":"Researcher","foaf:name":[{"@value":"Marilena Ferbinteanu"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666048","@type":"Researcher","foaf:name":[{"@value":"Takashi Kajiwara"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666057","@type":"Researcher","foaf:name":[{"@value":"Kwang-Yong Choi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666049","@type":"Researcher","foaf:name":[{"@value":"Hiroyuki Nojiri"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666051","@type":"Researcher","foaf:name":[{"@value":"Akio Nakamoto"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666050","@type":"Researcher","foaf:name":[{"@value":"Norimichi Kojima"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666054","@type":"Researcher","foaf:name":[{"@value":"Fanica Cimpoesu"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666056","@type":"Researcher","foaf:name":[{"@value":"Yuichi Fujimura"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666052","@type":"Researcher","foaf:name":[{"@value":"Shinya Takaishi"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137044963666053","@type":"Researcher","foaf:name":[{"@value":"Masahiro Yamashita"}],"jpcoar:affiliationName":[{"@value":"Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan, Institute for Materials Research, Tohoku University, Katahira 2-1-1, Sendai 980-8577, Japan, Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 113-8654, Japan, and CREST, Japan Science and Technology Agency (JST), Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00027863"},{"@type":"EISSN","@value":"15205126"}],"prism:publicationName":[{"@value":"Journal of the American Chemical Society"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2006-06-22","prism:volume":"128","prism:number":"28","prism:startingPage":"9008","prism:endingPage":"9009"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/ja062399i"}],"createdAt":"2006-06-22","modifiedAt":"2021-10-13","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216643918848","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Crystal Field Splitting of the Ground State of Terbium(III) and Dysprosium(III) Complexes with a Triimidazolyl Tripod Ligand and an Acetate Determined by Magnetic Analysis and 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H<sub>2</sub>O)Ln<sup>III</sup>(NO<sub>3</sub>)}<sub>2</sub>]·solvent [3-MeOsaltn = <i>N</i>,<i>N</i>′-Bis(3-methoxy-2-oxybenzylidene)-1,3-propanediaminato]"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283691620148608","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis, Structure, Luminescent, and Magnetic Properties of Carbonato-Bridged Zn<sup>II</sup><sub>2</sub>Ln<sup>III</sup><sub>2</sub> Complexes [(μ<sub>4</sub>-CO<sub>3</sub>)<sub>2</sub>{Zn<sup>II</sup>L<sup><i>n</i></sup>Ln<sup>III</sup>(NO<sub>3</sub>)}<sub>2</sub>] (Ln<sup>III</sup> = Gd<sup>III</sup>, Tb<sup>III</sup>, Dy<sup>III</sup>; L<sup>1</sup> = <i>N</i>,<i>N</i>′-Bis(3-methoxy-2-oxybenzylidene)-1,3-propanediaminato, L<sup>2</sup> = <i>N</i>,<i>N</i>′-Bis(3-ethoxy-2-oxybenzylidene)-1,3-propanediaminato)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694081933696","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and Magnetic Property of Copper(II)–Lanthanide(III) Complexes [{CuIILLnIII(<i>o</i>-van)(CH3COO)(MeOH)}2]·2H2O (LnIII = GdIII, TbIII, and DyIII; H3L = 1-(2-Hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane; <i>o</i>-van = 3-Methoxysalicylaldehydato)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360283694081982848","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis, Structures, and Magnetic Properties of Doubly Face-Sharing Heterotrinuclear NiII–LnIII–NiII (Ln = Eu, Gd, Tb, and Dy) Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360285707428689920","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Luminescent DyIII single ion magnets with same N6O3 donor atoms but different donor atom arrangements, ‘fac’-[DyIII(HLDL-ala)3]·8H2O and ‘mer’-[DyIII(HLDL-phe)3]·7H2O"}]},{"@id":"https://cir.nii.ac.jp/crid/1360567183079533056","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Circular and Chainlike Copper(II)–Lanthanide(III) Complexes Generated by Assembly Reactions of Racemic and Chiral Copper(II) Cross-Linking Ligand Complexes with Ln<sup>III</sup>(NO<sub>3</sub>)<sub>3</sub>·6H<sub>2</sub>O (Ln<sup>III</sup> = Gd<sup>III</sup>, Tb<sup>III</sup>, Dy<sup>III</sup>)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846641573520640","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Syntheses, Structures, and Magnetic Properties of Acetato- and Diphenolato-Bridged 3d–4f Binuclear Complexes [M(3-MeOsaltn)(MeOH)<sub><i>x</i></sub>(ac)Ln(hfac)<sub>2</sub>] (M = Zn<sup>II</sup>, Cu<sup>II</sup>, Ni<sup>II</sup>, Co<sup>II</sup>; Ln = La<sup>III</sup>, Gd<sup>III</sup>, Tb<sup>III</sup>, Dy<sup>III</sup>; 3-MeOsaltn = <i>N,N</i>′-Bis(3-methoxy-2-oxybenzylidene)-1,3-propanediaminato; ac = Acetato; hfac = Hexafluoroacetylacetonato; <i>x</i> = 0 or 1)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644026925952","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Cyclic and Linear Structures Constructed by Ionic Bonds between Alkali Ion and Pinwheel Pentanuclear [GdIII(CuIIL)4] Core of M[GdIII(CuIIL)4] (M+ = Na+, K+, and Cs+; H3L = <i>N</i>-(4-Methyl-6-oxo-3-azahept-4-enyl)oxamic Acid)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658558855168","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"A series of Cu<sup>II</sup>–Ln<sup>III</sup> complexes of an N<sub>2</sub>O<sub>3</sub> donor asymmetric ligand and a possible Cu<sup>II</sup>–Tb<sup>III</sup> SMM candidate in no bias field"}]},{"@id":"https://cir.nii.ac.jp/crid/1361975846893729920","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Interactions of Ruthenium(III) Complexes Bearing Bis(2-pyridylcarbonyl)aminate with Cations at the Carbonyl Group"}]},{"@id":"https://cir.nii.ac.jp/crid/1520573330856370944","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Cyclic and linear structures constructed by ionic bonds between alkali ion and pinwheel pentanuclear 〔Gd[3](Cu[2]L)4〕 core of M〔Gd[3](Cu[2]L)4〕 (M[+] = Na[+], K[+], and Cs[+]; H3L = N-(4-methyl-6-oxo-3-azahept-4-enyl)oxamic acid)"},{"@language":"ja-Kana","@value":"Cyclic and linear structures constructed by ionic bonds between alkali ion and pinwheel pentanuclear Gd 3 Cu 2 L 4 core of M Gd 3 Cu 2 L 4 M Na K and Cs H3L N 4 methyl 6 oxo 3 azahept 4 enyl oxamic acid"}]},{"@id":"https://cir.nii.ac.jp/crid/1521136279913959040","@type":"Article","relationType":["isCitedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and Magnetic Property of Copper(II)-Lanthanide(III) Complexes[{Cu〔II〕LLn〔III〕(o-van)(CH3COO)(MeOH)}2]・2H2O(Ln〔III〕=Gd〔III〕, Tb〔III〕, and Dy〔III〕;H3L=1-(2-Hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane; o-van=3-Methoxysalicylaldehydato)"},{"@language":"ja-Kana","@value":"Synthesis and Magnetic Property of Copper 2 Lanthanide 3 Complexes Cu 2 LLn 3 o van CH3COO MeOH 2 2H2O Ln 3 Gd 3 Tb 3 and Dy 3 H3L 1 2 Hydroxybenzamido 2 2 hydroxy 3 methoxybenzylideneamino ethane o van 3 Methoxysalicylaldehydato"}]},{"@id":"https://cir.nii.ac.jp/crid/1881709542690350336","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 620048: Experimental Crystal Structure 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