{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137045304800640.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/om0400494"}},{"identifier":{"@type":"URI","@value":"https://pubs.acs.org/doi/pdf/10.1021/om0400494"}}],"dc:title":[{"@value":"Reductive Cleavage of the N−N Bond of Hydrazine Induced by a Cationic Trinuclear Ruthenium Hexahydride Complex, [(Cp‘Ru)<sub>3</sub>(μ-H)<sub>6</sub>]X (Cp‘ = η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>; X = <sup>1</sup>/<sub>2</sub> SO<sub>4</sub>, BF<sub>4</sub>, PF<sub>6</sub>, BPh<sub>4</sub>) and Dihydrogen"}],"description":[{"notation":[{"@value":"The reaction of the monocationic triruthenium hexahydride [(Cp‘Ru)3(μ-H)6]X (1; X = 1/2 SO4, BF4, PF6, BPh4) with hydrazine leads to the formation of the mono(μ3-imido) complex (Cp‘Ru)3(μ3-NH)(μ-H)3 (3) and the triruthenium pentahydride complex (Cp‘Ru)3(μ3-H)2(μ-H)3 (2). Complex 1 is in equilibrium with 2 in the presence of NH4X or N2H5X, and complex 1 is regenerated upon treatment of 2 with such a protic salt. Complex 3 further reacts with hydrazine to yield the bis(μ3-imido) complex (Cp‘Ru)3(μ3-NH)2(μ-H) (4) as a result of cleavage of the nitrogen−nitrogen bond, which is formally catalyzed by a proton. Both 3 and 4 undergo hydrogenation to generate 2 together with ammonia. Thus, reductive cleavage of the nitrogen−nitrogen bond of hydrazine leading to ammonia is achieved by the use of the monocationic trinuclear hexahydride complex 1 and dihydrogen under conditions without any added proton source and a reducing agent."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137045304800642","@type":"Researcher","foaf:name":[{"@value":"Yumiko Nakajima"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology and CREST, Japan Science and Technology Corporation (JST), O-okayama, Meguro-ku, Tokyo 152-8552, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137045304800641","@type":"Researcher","foaf:name":[{"@value":"Akiko Inagaki"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology and CREST, Japan Science and Technology Corporation (JST), O-okayama, Meguro-ku, Tokyo 152-8552, Japan"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137045304800640","@type":"Researcher","foaf:name":[{"@value":"Hiroharu Suzuki"}],"jpcoar:affiliationName":[{"@value":"Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology and CREST, Japan Science and Technology Corporation (JST), O-okayama, Meguro-ku, Tokyo 152-8552, Japan"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"02767333"},{"@type":"EISSN","@value":"15206041"}],"prism:publicationName":[{"@value":"Organometallics"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2004-07-13","prism:volume":"23","prism:number":"17","prism:startingPage":"4040","prism:endingPage":"4046"},"reviewed":"false","url":[{"@id":"https://pubs.acs.org/doi/pdf/10.1021/om0400494"}],"createdAt":"2004-08-09","modifiedAt":"2023-03-23","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360004233213168896","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and N–H Reductive Elimination Study of Dinuclear Ruthenium Imido Dihydride Complexes"}]},{"@id":"https://cir.nii.ac.jp/crid/1360004233556461312","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Quest for metal/NH bifunctional bioinspired catalysis in a dinuclear platform"}]},{"@id":"https://cir.nii.ac.jp/crid/1360846644035570560","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and Properties of Diruthenium Tetrahydrides Supported by Less-substituted, Sterically Demanding Poly-<i>tert</i>-butylated Cyclopentadienyls"}]},{"@id":"https://cir.nii.ac.jp/crid/1360848658536595968","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis and characterisation of tetranuclear ruthenium polyhydrido clusters with pseudo-tetrahedral geometry"}]}],"dataSourceIdentifier":[{"@type":"CROSSREF","@value":"10.1021/om0400494"},{"@type":"OPENAIRE","@value":"doi_dedup___::a5f5c43ab760673d2399f26d46a80636"},{"@type":"CROSSREF","@value":"10.1039/b927357c_references_DOI_UK7kFopFfPIQNEUChBBghruSM2i"},{"@type":"CROSSREF","@value":"10.1021/ja3005682_references_DOI_UK7kFopFfPIQNEUChBBghruSM2i"},{"@type":"CROSSREF","@value":"10.1039/c6dt04523e_references_DOI_UK7kFopFfPIQNEUChBBghruSM2i"},{"@type":"CROSSREF","@value":"10.1246/cl.130699_references_DOI_UK7kFopFfPIQNEUChBBghruSM2i"}]}