{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1361137045484036736.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1016/j.molcatb.2003.11.003"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S1381117703002881?httpAccept=text/xml"}},{"identifier":{"@type":"URI","@value":"https://api.elsevier.com/content/article/PII:S1381117703002881?httpAccept=text/plain"}}],"dc:title":[{"@value":"Photochemical synthesis of formic acid from CO2 with formate dehydrogenase and water-soluble zinc porphyrin"}],"description":[{"notation":[{"@value":"Abstract   Photochemical synthesis of formic acid was investigated from hydrogen carbonate ion with formate dehydrogenase (FDH) from Saccharomyces cerevisiae and methylviologen (MV2+) photoreduction by the visible light photosensitisation of zinc tetrakis(4-methylpyridyl) porphyrin (ZnTMPyP) in the presence of triethanolamine (TEOA) as an electron donating reagent. Irradiation of a solution containing TEOA, ZnTMPyP, MV2+, sodium hydrogen carbonate and FDH with visible light resulted in formic acid synthesis. The concentration of formic acid was 62 μM after 3 h irradiation under the condition of 30 μM MV2+, 20 units FDH and pH 8."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1381137045484036736","@type":"Researcher","foaf:name":[{"@value":"Rie Miyatani"}]},{"@id":"https://cir.nii.ac.jp/crid/1381137045484036737","@type":"Researcher","foaf:name":[{"@value":"Yutaka Amao"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13811177"}],"prism:publicationName":[{"@value":"Journal of Molecular Catalysis B: Enzymatic"}],"dc:publisher":[{"@value":"Elsevier BV"}],"prism:publicationDate":"2004-02","prism:volume":"27","prism:number":"2-3","prism:startingPage":"121","prism:endingPage":"125"},"reviewed":"false","dc:rights":["https://www.elsevier.com/tdm/userlicense/1.0/","https://www.elsevier.com/legal/tdmrep-license"],"url":[{"@id":"https://api.elsevier.com/content/article/PII:S1381117703002881?httpAccept=text/xml"},{"@id":"https://api.elsevier.com/content/article/PII:S1381117703002881?httpAccept=text/plain"}],"createdAt":"2003-12-16","modifiedAt":"2025-10-24","relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360002216901061248","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"The effect of the functional ionic group of the viologen derivative on visible-light driven CO2 reduction to formic acid with the system consisting of water-soluble zinc porphyrin and formate 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Porphyrin"},{"@language":"ja","@value":"亜鉛ポルフィリンの光増感作用とアルコール脱水素酵素を利用したホルムアルデヒドからの光化学的メタノール合成"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681433939712","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"人工光合成系による二酸化炭素の還元・物質生産"},{"@language":"en","@value":"Artificial Photosynthesis for Carbon Dioxide Reduction and Conversion"},{"@language":"ja-Kana","@value":"ジンコウ コウゴウセイケイ ニ ヨル ニサンカ タンソ ノ カンゲン ・ ブッシツ セイサン"}]},{"@id":"https://cir.nii.ac.jp/crid/1390288547259202176","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Mechanistic Study of Hydrogen Production Based on the Formate Decomposition with Platinum Nanoparticles Dispersed by 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